Kinetic Studies on the Change of Fructose from the Rice Stored at Fluctuating Temperature Conditions

백미 변온 저장중 과당의 변화

  • 정연화 (부산여자대학교 식품영양학과) ;
  • 강문선 (부산여자대학교 식품영양학과) ;
  • 김무남 (부산여자대학교 식품영양학과) ;
  • 전순실 (순천대학교 식품영양학과)
  • Published : 1993.12.01

Abstract

Kinetic studies were performed to investigate free-fructose content change in rice during storage. The rice was stored at various water activities(0.44, 0.52, 0.65 and 0.75) and at fluctuating temperature($30/50^{\circ}C$) over period of 22 weeks. At early stage of storage free-furctose content increased by zero-order reaction, whereas at later stage, it decreased by first-order reaction. The reaction rates were positively related to water activity and/or temperature during storage. Activation energies calculated at range of aw 0.44~0.75 were found to be 10.76~19.56kcal/mole and 4.53~8.40kcal/mole, for the period of increase and decrease in the free-fructose contents, respectively. The shelf-life assessed at $25^{\circ}C$ was found to be 252(aw 0.44), 212 (aw 0.52), 193(aw 0.65) and 162(aw 0.75) days.

변온 조건하에서 백미를 저장했을때 수분활성에 따른 과당의 변화를 고찰한 결과를 요약하면 다음과 같다. 과당은 저장 초기에 0차반응으로 증가하다가 일정시간 이후 1차반응으로 감소하였다. 반응속도는 수분 활성과 자장온도가 높을수록 빨랐고, 각 수분활성에서의 활성화에너지는 과당 증가시 10.76~19.56, 감소시는 4.53~8.40kcal/mole이었다. 그리고 $Q_{10}$값은 증가시 1.74~2.74, 감소시는 1.26~1.54였다. Accelerated shelf-life test로 부터 구한 $25^{\circ}C$에서의 shelf-life는 수분활성 (0.44, 0.52, 0.65, 0.75)에 따라 252, 212, 193, 162일의 범위였으며, 온도와 수분활성이 증가함에 따라 단축되었다. 변온조건에서의 실측치와 예측치를 비교한 결과 유효 온도차는 과당 증가시 0.49~2.52, 감소에서는 1.03~2.02의 차이를 보였다.

Keywords

References

  1. Korean J. Food Sci. Technol. v.11 no.2 Radical distribution of Ca, P, Fe, vitamin B₁, B₂in the degermed brown rice kernel Kim,S.K.;Choi,H.S.
  2. Korean J. Food Sci. Technol. v.11 no.3 Mercury and cadmium concentration of brown rice produced in Korea Yang,J.S.;Lee,S.R.;Rho,C.S.
  3. Korean, J. Food Sci. Technol. v.10 no.4 Studies on the amino acid composition of Korean Foods Kim,E.S.;Im,K.J.;Park,H.;Chun,S.K.
  4. Korean J. Food Sci. Technol. v.10 no.2 Physicochemical properties of Tongil and Paldal rice starch Kim,S.K.;Hahn,T.R.;Lee,Y.H.;D'Appolonia,B.L.
  5. J. Korean Assoc. Food Sci. v.1 no.1 Studies on the preservation of Korean rice by γ-irradiation Kim,H.S.;Choi,Y.R.
  6. Korean J. Food Sci. Technol. v.8 no.2 Changes in eating quality and lipid components of Tongil rice variety in storage Hwangbo,J.S.;Lee,S.R.
  7. Bulletin of Pusan women's Uni. v.24 Changes of sucrose in rice stored under fluctuating temperature as a fuction of water activity Kim,M.N.;Jung,Y.H.;Chun,S.S.
  8. Bulletin of Pusan women's Uni. v.34 Kinetic studies on the changes of glucose from the rice stored at various water activities and fluctuating temperature conditions Jung,Y.H.;Chun,S.S.;Kim,M.N.
  9. Nanrung v.3 Paste formation in starch.Ⅳ. Effect of dehydrating agents and grain size on the paste forming properties of potato starch Taufel,K.;Hollo,J.;Szejtli,J.;Laszlo,E.;Toth,M.
  10. Am. Potato J. v.55 Relationships of harvest sucrose content to processing maturity and storage life of potatoes Sowokins,J.R.
  11. J. Agr. Food Chem. v.33 Effect of irradiation on the sucrose accumulation in potatoes Hayashi,T.;Aoki,S.
  12. Proc. 3rd Int. Cong. Food Sci. and Tech. SOS/70 Properties of water as related to the keeping quality of foods Labuza,T.P.
  13. Food Technol. v.23 Water activity and torage stability Rockland,L.B.
  14. Food Technol. v.31 no.10 Rapid analysis of carbohydrates by HPLC Edward,C.C.;Palmer,J.K.
  15. Korean J. Food Sci. Technol. v.15 no.1 Effect of relative humidities on the white ginseng during storage.Ⅱ. On the changes of saponins and sugars Noh,H.W.;Do,J.H.;Km,S.D.;Oh,H.I.
  16. Cereal Chem. v.57 no.2 Soybean quality changes during model storage studies Saio,K.;Nikkun,I.;Ando,Y.;Otsuru,M.;Terauchi,Y.;Kito,M.
  17. J. Food Sci. v.47 no.6 Accumulation of sucrose in γ-irradiated sweet potato roots Hayashi,T.;Kawashima,K.
  18. Cereal Chem. v.59 no.2 Effect of sugar on starch gelatinization Spies,R.D.;Hoseney,R.S.
  19. J. Food Sci. v.48 Starch sugar transformation during banana ripening : The behavior of UDP-glucose pyrophosphorylase, sucrose synthetase and invertase Terra,N.N.;Garcia,E.;Lajolo,F.M.
  20. J. Korean Soc. Food Nutr. v.13 no.2 Available lysine loss in rice stroied under fluctuation temperature as function of water activity Kim,M.N.;Kang,M.S.;Chun,S.S.
  21. J. Counc. Sci. Ind, Research v.17 Note on the estimation of the effect of diurnal temperature fluctuation on reaction rates in stored food stuff and other materials Hicks,E.W.
  22. Ind. Eng. Chem. v.27 no.6 Temperature tolerance for frozen food processing;Effective temperature in thermally fluctuating systems Schwimmer,S.;Ingrahm,L.L.;Hughes,H.W.
  23. J. Food Sci. v.30 Chemical and microbial activity ratio under square-wave simusoidal temperative fluctuation Powers,J.J.;Lukaszewica,W.;Wheeler,R.;Dorusetter,T.P.
  24. J. Food Sci. v.39 Effect of fluctuating temperature on the stability and activity of invertase Wu,A.C.M.;Eitenmiller,R.R.;Powers,J.J.
  25. J. Food Sci. v.40 Response of chymotrypsin and lysozyme under fluctuating temperature treatments Wu,A.C.M.;Eitenmiller,R.R.;Powers,J.J.
  26. J. Food Sci. v.44 A theoretical comparison of loss in foods under fluctuating temperature sequences Labuza,T.P.
  27. Cereal Chem. v.59 no.2 Kinetics of protein quality change in egg noodles stored under constant and fructuating temperatures Labuza,T.P.;Bohnsak,K.;Kim,M.N.
  28. J. Korean Soc. Food Nutr. v.11 no.3 Non-enzymatic browning reacting of the dried file fish Chun,S.S.;Kim,M.N.;Lee,K.H.