Application of Sol-Gel Coating Process in Pressureless Sintering of Si3N4 and Their Properties

알루미나 졸-겔 코팅 공정을 이용한 질화규소의 상압소결 및 물질 특성

  • 임경란 (한국과학기술연구원 세라믹스연구부) ;
  • 임창섭 (한국과학기술연구원 세라믹스연구부)
  • Published : 1994.01.01

Abstract

Si3N4 ceramics could be densified above 3.2g/㎤ with pressureless sintering at below 178$0^{\circ}C$ by coating Si3N4 and Y2O3 powder with an alumina sol. Substitution a portion of Al2O3 with AlN improved densification. Additional milling of the coated powder in large improvement in bending strength greater than 800 MPa (4-point).

Keywords

References

  1. J. Mater. Sci. v.24 Sinter and Sinter-HIP of Silicon Nitride Ceramics with Yttria and Alumina Additions I. Iturriza;F. Castro;M. Fuentes
  2. Am. Ceram. Soc. Bull. v.57 High Strength Hot-Pressed Si₃N₄with Concurrent Y₂O₃and Al₂O₃ Additions A. Tsuge;K. Nishida
  3. Adv. Ceram. Mat. v.3 no.5 Effect of N₂ Pressure Sintering on the Surface and Strength of Si₃N₄ N. Hirosaki
  4. Acta Crystallogr. v.B35 The Crystal Structure of β-Si₃N₄ R. Grun
  5. Mater. Res. Bull. v.9 Re-Examination of the Crystal Structure of α-Si₃N₄ I. Kohatsu;J.W. McCauley
  6. J. Am. Ceram. Soc. v.58 Structural Approach to the Problem of Oxygen Content in Alpha Silicon Nitride K. Kato;Z. Inoue;K. Kijimaja;I. Kawada;H. Tanaka;T. Yamane
  7. J. Mater. Sci. v.13 The α/β Silicon Nitride Phase Transformation D.R. Messier;F.L. Riley;R.J. Brook
  8. Materials Science Forum v.47 Thermo-mechanical Properties of Silicon Nitride and their Dependence on Microstructure G. Ziegler
  9. Materials Science Forum v.47 Microstructural Development in Silicon Nitride Ceramics C.J. Hwang;T. Tien
  10. Materials Science Forum. v.47 Evolution of Applications of Si₃N₄-Based Materials D.W. Richerson;P.H. Stephan
  11. J. Am. Ceram. Soc. v.64 no.12 Preparation of High Density Si₃N₄ by a Gas-Pressure Sintering Process C. Greskovich
  12. J. Am. Ceram. Soc. v.75 SiAlON Ceramics T. Ekstrom;M. Nygren
  13. J. Am. Ceram. Soc. v.59 Fracture Toughness Determination by Indentation A.G. Evans;E.A. Charles
  14. Am. Ceram. Soc. Bull. v.58 Preparation and Characterization of Ultrafine Powders of Refractory Nitrides : II, Sialon M. Hoch;K.M. Nair