Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지

Formation and Color of the Spinel Solid-Solution in $ZnO-Fe_2O_3-TiO_2-SnO_2$ System

$ZnO-Fe_2O_3-TiO_2-SnO_2$계 Spinel 안료 고용체의 생성과 발색

  • 박철원 (한양여자전문대학 도자기공예과) ;
  • 이진성 (한양여자전문대학 도자기공예과) ;
  • 이웅재 (한양여자전문대학 도자기공예과)
  • Published : 1994.02.01
Download PDF
⟨ Previous Next ⟩

Abstract

The formations of spinel and colors of ZnO-Fe2O3-TiO2-SnO2 system have been researched on the basis of ZnO-Fe2O3 system. Specimens were prepared by substituting Fe3+, with Ti4+ or Sn4+ when mole ratios between Fe3+ and Ti4+ or between Fe3+ and Sn4+ were 0.2 mole. The reflectance measurement and X-ray diffraction analysis of the formation of spinel and the colors of there specimens were carried out. ZnO-Fe2O3 system in which Fe2O3 was substituted with SnO2 and TiO2 was formed the spinel structure of 2ZnO.TiO2, 2ZnO.SnO2, ZnO.Fe2O3. The stable stains which were colored with yellow and brown could be manufactured.

Keywords

References

  1. 日窯協誌 v.73 no.9 錫スピネルの生成と發色とにおよばす錫イォンの配位選擇性の影響 大塚淳
  2. 日窯協誌 v.73 no.8 $CO^{2+},Ni^{2+}$ を含むマグネシウム-亞鉛系 チタンスピネルの生成と發色 大塚淳
  3. 日窯協誌 v.74 no.5 $CO^{2+},Ni^{2+}$ を含むチタン-クロムスピネルの生成と發色 大塚淳
  4. 日窯業誌 v.74 no.3 $CO^{2+},Ni^{2+}$ を含むチタン-錫スヒネルの生成と發色 大塚淳
  5. 日窯協誌 v.70 no.4 チタン-錫およびアルミニウム-クロム系スピネル顔料 大塚淳
  6. 日窯協誌 v.73 no.11 $CO^{2+},Ni^{2+}$ を含むチタン-錫スピネルの生成と發色 大塚淳
  7. 窯業會誌 v.12 no.1 Spinel Pigment의 生成反應에 관한 硏究 李應相;朴哲元;黃聖淵
  8. 窯業會誌 v.13 no.2 MgO-SnO₂系 Spinel 顔料에 대한 N₁O,TiO₂의 影響 李應相;朴哲元;黃聖淵
  9. Handbook of Colorimetry A.C.Hardy
  10. Philps Resch Repts. v.8 Physical and Crystallographical Properties of Some Spinel F.C.Romeijn
  11. Phys Rev Theory of Ionic Odering,Crystal Distortion, and Magnetic Exchange due to Covalent Process in Spinels J.B.Yoodenough;A.L.Loeb
  12. J.Appls v.30 no.40 Distribution of Cations in Spinels Arther Miller
  13. 日窯協誌 v.81 no.2 CoO-ZnO-Al₂O₃-Cr₂O₃-Fe₂O₃系 におけるスピネル固溶體の生成とその色 大塚淳
  14. 日窯協誌 v.82 no.2 CoO-MgO-Cr₂O₃-TiO₂-SnO₂系 スピネル固溶體の 生成と發色 大塚淳;藤橋雄一郞