Fabrication and Bi-Sr-Ca-Cu-O Superconducting Thin Films by RF Magnetron Sputtering

RF-Magnetron Sputtering에 의한 Bi-Sr-Ca-Cu-O 초전도 박막의 제조

  • 홍철민 (전남대학교 무기재료공학과) ;
  • 박현수 (전남대학교 무기재료공학과)
  • Published : 1994.02.01

Abstract

The Bi-Sr-Ca-Cu-O thin films were deposited by RF-magnetron sputtering method on Si(P-111) wafer without a buffer layer and annealed at various temperatures in oxygen atmosphere. The temperature dependence of electrical resistance, the microstructure of intermediate phase, and the surface morphology of films were examined by four probe method, XRD, and SEM, respectively. The chemical composition and the depth profile of the films were determined by ESCA spectra. Thin films annealed at $600^{\circ}C$ and $700^{\circ}C$ in oxygen atmosphere showed onset temperatures of 90 K and 85K, and Tc(zero) of 22K and 31K, respectively. The sample annealed at $700^{\circ}C$ had the highest volume fraction of superconducting phase and showed smooth microsturcture. In ESCA spectra, the thin films were homogeneous with depth.

Keywords

References

  1. Advances in Superconductivity Epitaxial Y-Ba-Cu-O Films on Si with Intermediate Layer by RF Magnetron Sputtering S.Miura;H.Tsuge;T.Yashitake;S.Matsubra
  2. Advances in Superconductivity Properties of Superconducting Bi-Sr-Ca-Cu-O Thin Films Prepared by Controlling Sputtering Condition and Annealing Atmospheres K.Ohbayashi;T.Ushida;T.Tsunooka;K.Ohya;H.Banno
  3. Advances in Superconductivity Preparation and Electrical Properties of 107K-BiSrCaCuO Superconducting Thin Films M.Mukaida;K.I.Kurada;S.Miyazawa
  4. J.Am Ceram.Soc. v.74 no.1 Processing and Characterization of Thin Films of the Two-Layer Superconducting Phase in the Bi-Sr-Ca-Cu-O System S.J.Golden;T.E.Bloomer;F.F.Lange;A.K.Cheetham
  5. J.Appl.Phys. v.67 no.8 In-Situ Deposition of BaF₂as a Buffer Layer and the Superconducting Thin Films of Y-Ba-Cu-O on Silicon Substrate by Chemical Vapor Deposition R.Singh;S.Sinha;N.J.Hsu;P.Chou
  6. Advances in Superconductivity High-T. Superconductor Prepared by Chemical Vapor Deposition K.Shinohara;F.Munakata;M.Yamawaka
  7. Advances in Superconductivity CVD of Bi-Sr-Ca-Cu-O Thin Films T.Kimura;M.Ihara;K.Ikeda;M.Ozeki
  8. Advances in Superconductivity Superconducting Thin Filmsl of $YBa_2Cu_3O_7$ and $ErBa_2Cu_3O_7$ Grown by Molecular Beam Epitaxy R.Cabanel;J.P.Hirtz;H.Teherani;G.Creuzet
  9. Advances in Superconductivity Preparation of 107 K Superconducting Thin Film in Bi-Sr-Ca-Cu-O System by Coevaporation T.Yoshitake;T.Satoh;Y.Kobu;H.Igarashi
  10. Advances in Superconductivity Formation of Crystallized Buffer Layer for High-$T_c$. Superconducting Thin Film J.Shinohara;Y.Ikegami;T.Kawamoto
  11. Meterials Research Society Laser Ablation for Meterials Synthesis David C Paine;Jhon C.Bravman
  12. J.Am Ceram.Soc. v.73 no.4 Formation of High-Tс. Superconducting Bi-Sr-Ca-Cu Oxide Thin Films by Spray Pyrolysys of an Oxalate Suspension F.H.Chen;T.Y.Teng
  13. Jpn.J Appl Phys. v.30 no.5A Formation of High-$T_c$Phase in Pb-Free Bi-Sr-Ca-Cu-O Thin Films S.Nagai;N.Fugimura;T.Iro;K.Shiraish
  14. Jpn.J.Appl.Phys v.28 no.9 Suface Mophology and Crystl Structures of As-Grown BiSrCa-CuO Thin Films Prepared by RF Magnetron Sputtering form Three Targets Kenichi Kuroda;Kazuyoshi Kojima;Masami Tanioku;Kazuo Yokoyama;Kichi Hamanaka
  15. J.Am.Ceram.Soc. v.72 no.5 Partial Bi-Sr-Cu-O Subsolidus Diagram at 800℃ with and Without Lithium Carbonate J.A.Saggio;K.Sujata;J.Hahn;S.J.Hwu;K.R.Poeppelmeier;T.O.Mason
  16. J.Am.Soc. v.72 no.12 Retrograde Densification in Bi₂Sr₂CaCu₂O Superconductor D.W.Johnson,Jr.;W.W.Rhodes
  17. J.Am.Ceram.Soc. v.75 no.5 2223 Phase Formation in Bi(Pb)-Sr-Ca-Cu-O II. The Role of Temperature -Reaction Machanism Yan Ling Chen;Ronald Stevens
  18. J Am Ceram Soc. v.73 no.6 Rapid Formation of the 110 K Phase in Bi-Pb-Sr-Ca-Cu-O Through Freeze Drying Powder Processing Kang-Ho Song;Hua-Guk Liu;Shi-Xue Dou;Charles C.Sorrell
  19. Advances in Superconductivity Structural Investigation of the High Tc Bi-Sr-Ca-Cu-O M.Matsui;H.Itoh;J.Liu;T.Shimizu;H.Matsuoka;K.Ohmori;M.Doyama