Optimization of Electrical Conductivity and Fracture Toughness in $Y_2O_3-Stabilized$ $ZrO_2$ through Microstructural Designs

이트리아 안정화 지르코니아에서 미세조직 설계에 따른 전기전도도와 파괴인성치의 적정화

  • Published : 1994.07.01

Abstract

Using two kinds of ZrO2 powder stabilized by 8 mol% and 3 mol% of Y2O3 several microstructures were designed; two single composition specimens of 8 mol% Y2O3-ZrO3 and 3 mol% Y2O3-ZrO2 and five mixture specimens with multi-layered structure and particulate mixture structure at a mixing ratio of 1:1 by weight. Electrical conductivities were measured from 250 to 75$0^{\circ}C$ in air using an impedance analyser, and fracture toughness at room temperature using the indentation method. Making the mixture structures was more effective in enhancing fracture toughness than electrical conductivity. At low temperatures 3 mol% Y2O3-ZrO2 showed the highest values in both electrical conductivity and fracture toughness, while at high temperature the specimens of alternately stacked planar and coarse granulated structure were most favorable.

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References

  1. 공업화학 v.3 21세기의 새로운 에너지기술: 연료전지 최수현
  2. Z. Elektrochem. v.43 Ueber Brennstoff-Ketten Mit Festleitern E. Bauer;H. Pries
  3. J. Mater Sci. v.12 Stabilization of Tetragonal Phase in Polycrystalline Zirconia T.K. Gupta;J.H. Bechtold;R.C. Kuznicki;L.H. Cadoff;B.R. Rossing
  4. Science and Technology of Zirconia Ⅱ Microstructural Design of Zirconica Toughened Ceramics (ZTC) N. Claussen;N. Claussen(ed.);M. Ruehle(ed.);A.H Heuer(ed.)
  5. Science and Technology of Zirconia Ⅱ Microstructural Electrical Property Relationship in High-Conductivity Zirconias E.P. Butler;R.K. Slotwinski;N. Bonanos;J. Drennan;B.C.H. Steele
  6. 요업학회지 v.30 no.717 미세구조설계에 따른 이트리아 안정화 지르코니아의 전기적 성질변화 김선재;김경호;오석진;강대갑;국일현
  7. Proceedings on the 9th International Conference on Solid State Ionics Microstructural Designs and Electrical Properties of Y₂O₃-doped ZrO₂s S.J. Kim;K.H. Kim;S.J. Oh;T.K. Kang;I.H. Kuk
  8. Proceedings on the 9th International Conference on Solid State Ionics Physical, Microstructural, and Thermomechanical Prorerties of ZrO₂ Single Crystals R.P. Ingel;D Lewis;B.A. Bender;R.W. Rice
  9. 요업학회지 v.24 코디어라이트-SiC 위스커 복합재료에서 측정방법에 따른 파괴인성치의 변화 강대갑;Weisskopf
  10. Cermaic Hardness I.J McColm(Ed.)
  11. Cermaic Hardness