Synthesis of Tungsten Carbide Powders by SHS Method

SHS법에 의한 탄화텅스텐 분말 합성

  • Jun, H.B. (Dept. of Inorganic Materials Engieering Myung-Ji Univ) ;
  • Cho, D.H. (Institute of Ceramics Technologu, NITI) ;
  • Lee, H.B. (Dept. of Inorganic Materials Engieering Myung-Ji Univ) ;
  • Park, S. (Dept. of Inorganic Materials Engieering Myung-Ji Univ)
  • 전호병 (명지대학교 무기재료공학과) ;
  • 조덕호 (요업기술원) ;
  • 이형복 (명지대학교 무기재료공학과) ;
  • 박성 (명지대학교 무기재료공학과)
  • Published : 1994.10.01

Abstract

We powders were synthesized from W powders in differnet particle sizes by Self-propagating High-temperature Synthesis process (SHS) using a chemical furnace. The effects of the mole ratio of chemical fuel content, pellet thickness and the mole ratio between carbon and tungsten (C/W Ratio) on synthesis were investigated with the tungsten powders have different particle size each other. Compositional and structural characterization of these powders was carried out by scanning electron microscope (SEM0 and x-ray diffractometer. Powder characterization was carried out by the measurement of particle size distribution with laser-particle size analyzer. The amounts of WC obtained by SHS process depend very much on the particle size of tungsten powder and heat contents given in a product, i.e. as the particle size of W powder is smaller, the amounts of WC produced increase. Also the more heat contents is given, the more amounts of WC increase. By optimizing the synthesis conditions, it is possible to fabricate WC powders which have little secondary phases (W2C, C).

Keywords

References

  1. Science of Hard Materials Development and Present Status of the Science and Technology of Hard Materials H.F. Fischmeister;R.K. Viswanadham(ed.)
  2. The Refractory Carbides E.K. Storms(ed.)
  3. U.S. Patent No. 3,379,503 Macro Process for Direct Production of Tungsten Carbide E.N. Smith
  4. J. Am. Ceram. Soc. v.75 no.1 Synthesis, Sintering, Microstructure and Mechanical Properties of Ceramics Made by Exothermic Reactions R.A. Cutler;K.M. Rigtrup
  5. Ceram. Bull. v.67 no.2 Synthesis of High Temperature Materials by Self-propagating Combustion Methods Z.A. Munir
  6. U.S.S.R. Patent No. 584.052 Method for Obtaining Refractory Compounds A.G. Merzhanov(et al.)
  7. J. of. Am. Ceram. Soc. v.49 no.9 Effects of Explosive Shock Waves on Ceramic Powders O.R. Bergmann;J. Barrington