Preparations of $(Zr_{0.08}Sn_{0.2})TiO_4$ Dielectric Powders by Coprecipitation of $(Zr^{4+}, Ti^{4+})-Hydroxides in the Presence of SnO2 Particles

부분 공침법에 의한 $(Zr_{0.08}Sn_{0.2})TiO_4$ 분말합성 및 유전특성

  • 임경란 (한국과학기술연구원 세라믹스연구부) ;
  • 장진욱 (서울대학교 무기재료공학과)
  • Published : 1994.11.01

Abstract

(Zr, Sn)TiO4 powders were prepared in 0.05~0.13 ${\mu}{\textrm}{m}$ by coprecipitating (Zr4+, Ti4+)hydroxide on SnO2 particles and followed by calcination at 90$0^{\circ}C$ for 2 h. They sinter to 95% of relative density at 140$0^{\circ}C$ for 2 h. and shows dielectric constant, $\varepsilon$r=37.5 and quality factor, Qxf(GHz)=46,000. With 3 mol% of ZnO it sinters to rel=97.5%, $\varepsilon$r=39 and Qxf(GHz)=40,050 at 135$0^{\circ}C$ for 2 h., but raising sintering temperature to 140$0^{\circ}C$ deteriorates quality factor, relative density and microstructure with developing second phase.

Keywords

References

  1. Jap. J. Appl. Phys v.21 no.10 Ba(Mg⅓Ta⅔)O₃ Ceramics with Temperature-Stable High Dielectric Constant and Low Microwave Loss S. Nomnra;K. Toyama;K. Kaneta
  2. J. Am. Ceram. Soc. v.66 no.6 Ba(Zn⅓Ta⅔)O₃ Ceramics with Low Dielectric Loss at Microwave Frequencies S. Kawashima;M. Nishida;I. Ueda;H. Ouchi
  3. J. Am. Ceram. Soc. v.69 no.1 Far Infrared Reflection Spectra of Ba(Zn, Ta)O₃-BaZrO₃Dielectric Resonator Material K. Wakino;M. Murata;H. Tamura
  4. J. Am. Ceram. Soc. v.67 no.4 Microwave Characteristics of (Zr. Sn)TiO₄and BaO-PbO-Nd₂O₃-TiO₃Dielectric Resonators K. Wakino;K. Minai;H. Tamura
  5. Mat. Res. Bull. v.23 Microwave Dielectric Properties of (ZrSn)TiO₄Ceramics Y.C. Heiao;L.Wu;C.C Wei
  6. Ceramic Today-Tommorrow's Ceramic Sol-Gel Powders for Microwave Dielectric Resonators O. Renoult(et al.);P.Vincenzini(ed.)
  7. J. Am. Ceram. Soc. v.74 no.6 Chemical Processing and Microwave Characteristics of (Zr, Sn)TiO₄Microwave Dielectrics S. Hirano;T. Hayashi;A. Tattari
  8. Mat. Res. Bull. v.18 Existencr Range, Structural and Dielectric Properties of Zrx-TiySn₂O₄Ceramics (x+y+z=2) G. Wolfram;H.E. Gobel
  9. Br Ceram. Trans. J. v.89 Dielectric Resonator Materials and Their Applicatio for Mobile Communication Systems K. Wakino;T. Nishikawa;Y. Ishikawa;H. Tamura
  10. J. Am. Ceram. Soc. v.73 no.6 Dielectric Constant Characteristics of a New Composite Dielectric Matemal H. Koayashi;Y. Hosokawa
  11. J. Am. Ceram. Soc. v.53 no.5 Chemical Preparation of PLZT Powders from Aquous Nitrate Solution J. Thomson Jr.
  12. J. Ceram. Soc. Jap. v.101 no.1 Synthesis of PLZT Ceramics by the Coprecipitation Method and the Effect of Grinding on Synthesis and Sintering Behavior of Powders M. Awano;H. Takagi
  13. IRE Trans. Microwave Theory Techn. v.8 no.402 A Dielectric Resonator Method of Measuring Inductive Capacitance in the Millimeter Range B.W. Hakki;P.D. Coleman
  14. Br. Ceram. Proc. v.36 The Microstructure and Low frequency Dielectric Properties of Some Zirconium Titanium Stannate(ZTS) Ceramics F. Azough;R. Freer