Effect of the Calcination Conditions for the Synthesized $BaTiO_3$ Powder and the Sintered PTC Ceramics by Oxalic Acid Method

Oxalic Acid법으로 합성한 $BaTiO_3$ 분말과 소결한 PTC 세라믹스에 대한 하소조건의 효과

  • 이미재 (국립공업기술원 요업기술원) ;
  • 황선아 (국립공업기술원 요업기술원) ;
  • 최병현 (국립공업기술원 요업기술원)
  • Published : 1994.11.01

Abstract

The characteristic of calcined BaTiO3 powder and sintered PTC ceramics was investigated varing with calcination temperature and time of BaTiO(C2O4)2.4H2O synthesized from BaCl2.2H2O, TiCl4, oxalic acid and ethanol by oxalic acid method. When the particle size was less than 0.1 ${\mu}{\textrm}{m}$ by controlling calcination temperature and time, the resistance at room temperature was measured very high (above M{{{{ OMEGA }}). However, when the calcined particle sizes ranged from 0.2 to 0.3 ${\mu}{\textrm}{m}$, the resistance was 100 {{{{ OMEGA }} (After sintering, the grain size was 10~30 ${\mu}{\textrm}{m}$ homogeneously with the addition of dopant in sintering, the resistivity, resistance, $\alpha$ value and jumped to were 110{{{{ OMEGA }}.cm, 24$^{\circ}C$/% and 106{{{{ OMEGA }}, respectively.

Keywords

References

  1. International Tech Report v.25 no.5 高性能 PTC サミスタ材料 藤村正紀;松尾嘉浩
  2. エレクトロニク セラミクス v.104 高純度微粒子酸化物 芦村隆土
  3. J. Am. Ceram. Soc. v.72 no.10 Factors Affecting the Preparation of Barium Titanyl Oxalate Tetrahydrate Tsang-Tse Fang;Horng-Bin Lin
  4. エレクトロニク セラミクス v.104 水熱法 チタソ酸パリウム 靑木昌史;安倍一允
  5. Ceramics International v.11 no.1 Preperation of Barium Titanate by Oxalate Method in Ethanol Solution H.Yamamura;A. Watanabe;S. Shirasaki;Y. Moriyoshi;M. Tanada
  6. J. Res. Natl. Bur. Std. v.56 no.5 Preparation of Barium Titanyl Oxalate Tetrahydrate for Converaion to Barium Titanate of High Purity W.S. Clabaugh;E.M. Swiggard;R. Gilchrist
  7. J. Am. Ceram. Soc. v.46 Preparation of Semiconducting Titanates by Chemical Methods P.K. Gallagher;F.Schrey
  8. J. Am. Ceram. Soc. Bull v.61 no.1236 Preparation of Stoichiometric Barium Titanyl Tetrahydrate K. Kudaka(et al.)
  9. Yogyo-Kyokai-Shi v.91 no.1 Thermal Decomposition of Barium Titanium (Ⅳ) bis (Oxalate)Oxide and the Formation of Barium Titanate K. Iizumi;K. Sobata;K. Kudaka
  10. J. Japan. Phys. Soc. v.14 no.9 Properties of Semiconductive Barium Titanates O. Saburi
  11. エレクトロニク セラミッス v.4 PCT セラミックの製造法 松尾嘉浩;佐佐木宏
  12. セソサ技術 v.10 no.4 PCT サミスタの材料とその反應 津田泰男;玉井孝