Preparation of $Ba_{0.5}Sr_{0.5}TiO_3$ Thin Films by Off-Axis RF Magnetron Sputtering

Off-Axis RF Magnetron Sputtering 방법에 의한 $Ba_{0.5}Sr_{0.5}TiO_3$ 박막의 제조

  • Shin, Jin (Division of Electronics and Information Technology, Korea Intitute of Science and Technology) ;
  • Hahn, Taek-Sang (Division of Electronics and Information Technology, Korea Intitute of Science and Technology) ;
  • Kim, Young-Hwan (Division of Electronics and Information Technology, Korea Intitute of Science and Technology) ;
  • Lee, Jae-Jun (Division of Electronics and Information Technology, Korea Intitute of Science and Technology) ;
  • Park, Soon-Ja (Department of Inorganic Materials Engineering, Seoul National University) ;
  • Oh, Myung-Hwan (Division of Electronics and Information Technology, Korea Intitute of Science and Technology) ;
  • Choi, Sang-Sam (Division of Electronics and Information Technology, Korea Intitute of Science and Technology)
  • 신진 (한국과학기술연구원 정보전자연구부) ;
  • 한택상 (한국과학기술연구원 정보전자연구부) ;
  • 김영환 (한국과학기술연구원 정보전자연구부) ;
  • 이재준 (한국과학기술연구원 정보전자연구부) ;
  • 박순자 (서울대학교 무기재료공학과) ;
  • 오명환 (한국과학기술연구원 정보전자연구부) ;
  • 최상삼 (한국과학기술연구원 정보전자연구부)
  • Published : 1994.12.01

Abstract

We have prepared Ba0.5Sr0.5TiO3 thin films on Si substrate without buffer layer. Deposition was carried out by off-axis rf magnetron sputtering method using Ba0.5Sr0.5TiO3 stoichiometric target. The substrate temperature was changed from 40$0^{\circ}C$ to $700^{\circ}C$ during deposition. As the substrate temperature increased, relative intensity of (110) peak increased up to $600^{\circ}C$, however preferred orientation changed from (110) to (h00) beyond $650^{\circ}C$ of substrate temperature. Deposited films showed microstructures with fine grains whose diameters are less than 100 nm, and columnar structure was observed in the cross-sectional SEM micrograph. AES depth profile showed no significant diffusion at the interfacial reaction area. The effective dielectric constant of films showed maximum value at $600^{\circ}C$, and the leakage current increased with increasing substrate temperature, which may be ascribed to the crystallization of amorphous phases at grain boundary.

Keywords

References

  1. Appl. Phys Lett. v.57 no.22 Reactive Partially Ionized Beam Deposition of BaTiO3 Thin Films P. Li;T.M. Lu
  2. J. Am. Ceram. Soc. v.40 no.11 Phase Equilibria in the System BaTiO3-SrTiO3 A. Basjamin;R.C. DeVries
  3. Ferroelectrics and Related Substances a: Oxide K.H. Hellwege;A.M. Hellwege
  4. Ferroelectrics v.37 Fabrication of BaTiO₃ Films by Planar Magnetron Sputtering T. Nagamoto;T. Kosaka;S. Omori;O. Omoto
  5. ISAF Proc. (Ba, Sr)TiO₃ Thin Films by Multi-Ion-Beam Reactive Sputtering Technique C.J. Peng;H. Hu;S.B. Krupanidhi
  6. Appl. Phys Lett. v.59 no.27 Structural and Optical Properties of Sol-Gel Processed BaTiO3 Ferroelectric Thin Films M.N. Kamalasaman;S. Chandra
  7. J Elect Mat. v.20 no.11 High-Performance Barium Titanate Capacitor with Double Layer Structure Z.Q. Shi;Q.X. Jia;W.A. Anderson
  8. J. Mat. Sci. Materials in Electronics v.1 Preparation of Ferroelectric Thin Films by MOCVD Using Ultrasonic Spraying C.H. Lee;S.J. Park
  9. Jpn. J. Appl. Phys. v.30 no.9B Preparation and Properties of Lead-Zirconate Thin Films K. Iuima;I. Ueda;K. Kugimiya
  10. Physics of Semiconductork Device S.M. Sze