연소합성에 의한 크로메이트 내화물 제조

Chromate Refractory by Combustion Process

  • 김형순 (순천대학교 금속공학과) ;
  • 한정환 (제선연구실 산업과학기술연구소)
  • 발행 : 1994.12.01

초록

Self propagating synthesis and thermal explosion of combustion reactions were applied to Al/K2Cr2O7/Al2O3 system as the first stage for a production of magnesia-chromium refractory. Several factors related to products made by two combustion reactions were considered and properties of products were characterised. Two processes were required to preheat upto at least 80$0^{\circ}C$ for the thermal explosion and the self propagating synthesis. These processes were so violent and explosive that alumina as diluent was added to the system in order to absorb the reaction heat and reduce the reaction rate. The products consisted of crystal phases of KAl5O8, Cr2O3, Al2O3, K2CrO4, and K2Al2O4.3H2O. The amount of KAl5O8 and K2Al2O4.3H2O crystal phases of products were decreased with further addition of alumina.

키워드

참고문헌

  1. Combustion and Plasma Synthesis of High Temperature Materials Self-Propagating High Temperature Synthesis: Twenty Years of Search and Findings A.G. Merzahanov;Z.A. Munir(ed.);J.B. Holt(ed.)
  2. Mater. Sci. Rep. v.3 Self-Propagating Exothermic Reactions: The Synthesis of High-temperature Materials by Combustion Z.A. Munir;V Anselmi-Tamburini
  3. Taikabutsu v.44 no.2 Damage of Magnesia-Chromite Brick in Secondary Refining Furnace K. Tamaki
  4. Taikabutsu v.44 no.8 An Experimental on Compositions of Magnesia-Chromite Brick for AOD Tuyeres T. Tada;K. Maeda;M. Koyama
  5. Taikabutsu v.45 no.8 Improvement of Semi-rebonded Magnesia-Chrome Bricks T. Yamamura;H. Sugimoto;K. Minato;K. Saito
  6. Taikabutsu v.46 no.2 Magnesia-spinel Brick for Cement Rotary Kiln K. Nobuhara;H. Sugiyama;M. Takemoto;A. Ohta
  7. Am. Ceram. Soc. Bull. v.72 Magnesia-alumina-spinel Raw Materials Production and Preparation R.M. Evans
  8. Am. Ceram. Soc. Bull. v.67 Synthesis of High Temperature Materials by Self-propagating Combustion Methods Z.A. Munir
  9. J. Mater Sci v.27 Self-Propagating High-temperature Synthesis J. Subrahmanyam;M. Vijayakumar
  10. Encyclopaedia Chimica
  11. Principles of Extractive Metallurgy T. Rosenqvist
  12. Refractories Self-propagating High-temperature Synthesis. Combustion front, Dissemination and Structure V.I. Sumin;Y.N. Makurin
  13. Metallurgical Thermochemistry O. Kubaschewski;C.B Alock