Isolation and Physicochemical Properties of Carotenoid Pigments from Orange Peels

감귤 과피 Carotenoid 색소의 분리 및 이화학적 성질

  • Shim, Ki-Hwan (Dept. of Food Science and Technology, Gyeongsang National University) ;
  • Sung, Nack-Kie (Dept. of Food Science and Technology, Gyeongsang National University) ;
  • Kan, Kap-Suk (Dept. of Processing, Pusan Junior College) ;
  • Choi, Jine-Shang (Dept. of Food Science and Technology, Gyeongsang National University) ;
  • Jang, Chi-Won (Dept. of Food Science and Technology, Gyeongsang National University)
  • 심기환 (경상대학교 식품공학과) ;
  • 성낙계 (경상대학교 식품공학과) ;
  • 강갑석 (부산전문대학 식품가공과) ;
  • 최진상 (경상대학교 식품공학과) ;
  • 장치원 (경상대학교 식품공학과)
  • Published : 1994.02.01

Abstract

Carotenoids isolated from orange peels were determined physicocohemical properties with TLC, UV-spectrophotometer and HPLC etc., and the results were as follows . Maximum absorption wavelength of the isolated carotenoids was 415nm when the result was similar to $\beta$-carotene as 423nm. Eight spots were obtianed from TLC, and identified lutein, lycopene, $\alpha$-carotene and $\beta$-carotene with HPLC. The effect pH during the storage period of isolate carotenoids, the period when the amount of pigment retention was over 50% in pH 5, 6 and 7 , after 10 days . The amount of pigment retention was lower in control than in treatment of sugars such as fructose, glucose and sorbitol , but sucrose was similar to the control, Isolated carotenoids were stable to ascorbic acid, and the amount of pigment retention was over 70% after 10 days. The amount of pigment retention in the effect oforganic acid was higher in treated citric acid , lactic acid and tartaric acid than in control, but lower in treated maleic acid and succinic acid. Isolated carotenoids were stable at 50 $^{\circ}C$, and the amount of pigment retention was over 50% at 10$0^{\circ}C$.

Keywords

References

  1. 한국농화학회지 v.8 한국산 감귤류의 화학성분에 관한 연구(1) 양차범;범훈;김재욱
  2. 한국농화학회지 v.9 한국산 감귤류의 화학성분에 관한 연구(2) 박훈;김영섭
  3. 한국농화학회지 v.8 제주산 감귤의 산 및 당함량의 시기별 변화에 관한 연구 한해룡;김한림;강순선
  4. 한국식품과학회지 v.9 no.4 한국산 감귤파괴의 효율적 이용에 관한 연구(1) 장호남;서종화
  5. 한국식품과학회지 v.14 no.1 한국산 감귤류 폐과피내의 펙틴함량과 펙틴의 특성에 관한 연구 문수재;손경희;윤선;이명해;이명희
  6. USP, US. 4,497 Beverages obtained from alchohlic treatment of roasted Citrus fruit peels Ehrlich,J.R.;Hess,H.
  7. USP, US. 4,661 Debittering bran flakes using Citrus peel Meczkowski,F.J.;Triaini,R.T.
  8. J. Org. Chem. v.30 Citrus carotenoids(4) Henry,Y.;Michael,J.W.
  9. J. Food Sci. v.32 Comparison of carotenoids of mature green and yellow lemon Henry,Y.;Curl,E.V.
  10. J. Org. Chem. v.30 Citrus carotenoids(3) Henry,Y.;Curl,E.V.;Michael,J.W.
  11. Nippon Shokuhiu Kogyo Gakkaishi v.18 no.4 Carotenoid pattern of Citrus unshiu flesh analysis of orange juice(1,2,3,4) Umeda,K.;Tanaka,Y.;Ohira,K.
  12. Agric. Food Chem. v.2 no.13 Polyoxygen carotenoids of valencia orange juice Curl,A.L.
  13. J. Food Sci. v.26 The carotenoid of mayer lemons Curl,A.L.
  14. J. Food. Sci. v.32 Apo-10-violaxanthal, a new carotenoid from valencia orange peels Curl,A.L.
  15. J. Agric. Food Chem. v.5 The carotenoid of tangerines Curl,A.L.;Bailey,G.F.
  16. Food Res. v.31 Structure of the carotenoid neoxanthin Curl,A.L.;Bailey,G.F.
  17. J. Argic. Food Chem. v.25 no.5 Provitamin A and carotenoid content of orange juice Ivan,S.
  18. J. Chromatogr. v.157 High pressure liquid chromatography of carotenoids Ann,F.;Julius,T.M.;Synnove,L.J.
  19. Korean J. Food Sci. Technol. v.6 no.1 Studies on the extraction of natural compounds from plants and microorganisms Yu,J.H.;Hong,Y.M.;Yoo,S.K.;Kim,Y.S.
  20. Chromatographia v.17 no.3 Separation of Citrus carotenoid by reverse phase high performance liquid chromatography Noga,G.;Lenz,F.
  21. 한국농화학회지 v.25 no.1 재배 오미자의 anthocyanin과 그의 안정성에 관하여 양희천;이종문;송기걸
  22. J. Agric. Food Chem. v.40 Effect of food preparation on qualitative and quantitative distribution of major carotenoid constituents of tomatoes and several green Frederick,K.;Mudlagiri,B.G.;Gary,R.B.;Joanne,H.;William,R.L.;Maria,D.T.;Mercedes,R.B.
  23. Lebensm. Wis. Utechnol. v.17 Purification of Citrus peel pigment preparate by gel permeation chromatography Rosenberg,M.;Mannhein,C.H.;Kopelman,I.J.
  24. 한국영양식량학회지 v.11 no.2 나무딸기 anthocyanin 색소에 미치는 당류의 영향 주광지