Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Optical Third-Harmonic Generation of Poly(2-Bromo-1,4-phenylenevinylene)

  • Hwang Do-Hoon (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Lee Jeong-Ik (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Lee Minyung (Optics Laboratory, Korea Research Institute of Standards and Science) ;
  • Shim Hong-Ku (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • Published : 1994.01.20
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Abstract

Weakly electron withdrawing bromine substituted poly(2-bromo-1,4-phenylenevinylene) (PBrPV) was synthesized th-rough water-soluble precursor method. The linear and nonlinear optical properties of PBrPV were compared with those of poly(1,4-phenylenevinylene) (PPV). The third-order nonlinear optical susceptibility, X^{(3)}$, was measured by using third-harmonic generation (THG) technique at 1907 nm, fundamental wavelength. The calculated $X^{(3)}$ values of PPV and PBrPV were 3${\times}$ 10$^{-12}$ esu and 2${\times}$10$^{-12}$ esu, respectively.

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