Bulletin of the Korean Chemical Society

  • 제15권2호
  • /
  • Pages.115-118
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  • 1994
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Effects of Sb-Incorporation on the 2223 Phase in the Superconducting Bi-Pb-Sr-Ca-Cu-O System

  • 발행 : 1994.02.20
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초록

Samples of ($Bi_{2-x}Sb_x)PbSr_2Ca_2Cu_3O_y$, compositions with x=0.0, 0.1, and 0.2 were prepared by solid-state reaction. The solubility of Sb into the 2223 phase is lower than 0.05 for the ratio of Sb/Bi. The lack of stability of the Sb-substituted $Bi_2O_2$ double layers is likely to cause the solubility low. There is no great dependence of lattice parameters on the Sb-content, and bonds around the square-pyramidal Cu atom are not affected by the $Sb^{3+}$ ion substituted. The superconducting transition temperature of this system is decreased gradually with increase of Sb, which is tentatively attributable to the perturbation of the Bi 6p-O 2p band and/or to the low volume fraction of the 2223 phase.

키워드

참고문헌

  1. Jpn. J. Appl. Phys. v.27 Maeda, H.;Tanaka, Y.;Fukutomi, N.;Asano, T.
  2. Solid State Commun. v.69 Liu, H.;Cao, L.;Zhou, L.;Mao, Z.;Li, Z.;Yu, Z.;Xue, B;Mao, X.;Zhou, G.;Run, Y.;Chen, Z.;Zhang, Y.
  3. Solid State Commun. v.75 Chen, Z.;Mao, X.;Zhou, L.;Quin, Y.;Lin, R.;Cao, L.;Chen, Z.;Zhang, Y.
  4. Appl. Phys. Lett. v.55 Chandrachood, M. R.;Mulla, I. S.;Sinha, A. P. B.
  5. Appl. PHys. Lett. v.57 Wang, H.;Wang, X.;Shang, S.;Wang, Z.;Lu, Z.;Jiang, M.
  6. Physica v.C176 Xin, Y.;Sheng, Z. Z.;Nasrazadani, S.
  7. Phys. Lett. v.A139 Peng, W.;Hannon, R. H.;Lee, H.;Genis, A. P.;Melim, V. J.;Kimball, C. W.;Dabrowski, B.;Hinks, D. G.
  8. Appl. Phys. Left. v.58 Kijima, N.;Gronsky, R.;Endo, H.;Oguri, Y.;McKernan, S. K.;Zettl, A.
  9. J. Physica v.C152 Massidda, S.;Yu, J.;Freeman, A.
  10. Phys. Rev. v.B40 Lindberg, P. A. P.;Shen, Z.-X.;Dessau, D. S.;Wells, B. O.;Mitzi, D. B.;Lindau, I.;Spicer, W. E.;Kaptitulnik, A.
  11. J. Appl. Cryst. v.6 Langford, J. I.
  12. Structural Inorganic Chemistry Wells, A. F.
  13. Phys. Rev. v.B39 Piro, O. E.;Guida, J. A.;Massa, N. E.;Aymonino, P. J.;Castellano, E. E.;Basso, H. C.;Gallo, J. N. H.;Martin, A. A.
  14. Physica v.C157 Gupta, H. C.

피인용 문헌

  1. Sb-doped CuAlO2: widening of band gap and nonlinear J-E characteristics vol.46, pp.6, 1994, https://doi.org/10.1007/s10853-010-4975-5