Preparation and Characteristics of $(Ba_{1-x}Sr_x)TiO_3$ Thin Films by the Sol-gel Process

졸-겔법을 이용한 $(Ba_{1-x}Sr_x)TiO_3$ 박막의 제조 및 특성

  • 황규석 (전남대학교 공과대학 무기재료공학과) ;
  • 김병훈 (전남대학교 공과대학 무기재료공학과)
  • Published : 1995.04.01

Abstract

In this study, to prepare the dielectric (Ba, Sr)TiO3 thin films by the sol-gel process, Titaminum (IV) sio-propoxide (Ti[OCH(CH3)2]4), Ba and Sr acetate were used for sol and thin films were prepared by dip-coating process. Stability of sol decreased with the increase of Sr, and thickness of thin films were obtained 0.13~0.17${\mu}{\textrm}{m}$ by 1 coating cycle. Transmittance of amorphous thin films heated at 500 and 55$0^{\circ}C$ was very good, and crystallization tendency of thin films according to heat-treatment temperature and crystallization characteristics of thin films heated at 11$0^{\circ}C$ for 3 hrs were analysed. As a result, good perovskite structure was obtained higher than 100$0^{\circ}C$, and tetragonality of thin film was decreased but pyrochlore was formed with increasing Sr. In case of addition to substitute 0.4mol% Sr for Ba, dielectric constant was 288 and loss factor (tan $\delta$) was 0.04.

Keywords

References

  1. Appl. Phys. Lett. v.58 no.23 High charge storage in amorphous BaTiO₃thin films P. Li;T.M. Lu
  2. Appl. Phys. Lett. v.59 no.9 Direct observation of BaTiO₃microcrystallites in thin amorphous BaTiO₃films P. Li;T.M. Lu
  3. J. Appl. Phys. v.42 no.9 Dispersion of electro-optic effect in BaTiO₃ A.R. Johnston
  4. J. Appl. Phys. v.154 no.11 RF planar magnetron sputtering and characterization of ferroelectric Pb(Zr,Ti)O₃films S.B. Krupanidhi;N. Maffei;M. Sayer;K. El-Assal
  5. J. Mater. Sci. v.25 Low-temperature synthesis and processing of electronic materials in the BaO-TiO₂system P.P. Phule;S.H. Risbud
  6. J. Am. Ceram. Soc. v.73 no.3 Influence of stoichiometry on the microstructure and positive temperature coefficient of resistivity of semiconducting barium titanate ceramics T.F. Lin;C.T. Hu
  7. J. Am. Ceram. Soc. v.73 no.3 Electrical properties of PTCR barium titanate D.Y. Wang;K. Umeya
  8. J. Mater. Sci. Lett v.8 The effect of cooling rate on the positive temperature coefficent resistivity characteristics of lanthanum-doped Ba0.8Sr0.2TiO₃ceramics H.P. Chen;T.Y. Tseng
  9. J. Am. Ceram. Soc. v.75 no.3 Mixed oxide capacitor of CuO-BaTiO₃as a new type CO₂gas sensor T. Ishihara;K. Kometani;Y. Mizuhara;Y. Takita
  10. J. Am. Ceram. Soc. v.75 no.9 Calculation of ultraslow dielectric relaxation of doped BaTiO₃ceramics H. Sun;L. Zhang;X. Yao
  11. Appl. Phys. Lett. v.58 no.23 High charge storage in amorphous BaTiO₃thin films P. Li;T.M. Lu;H. Bakhru
  12. Appl. Phys. Lett. v.59 no.9 Direct observation of BaTiO₃microcrystallites in thin amorphous BaTiO₃films P. Li;T.M. Lu
  13. J. Am. Ceram. Soc. v.76 no.6 Chemical control of the grain boundary migration of SrTiO₃in the SrTiO₃-BaTiO₃-CaTiO₃ system K.J. Yoon;S.J. Kang
  14. J. Am. Ceram. Soc. v.76 no.9 Synthesis and processing characteristics of $Ba_{0.65}Sr_{0.35}$TiO₃powders from catecholate precusors Naser J. Ali;Steven J. Milne
  15. Advanced inorganic chemistry F.A. Cotton;G. Wilkinson
  16. Sol-gel technology for thin films, fibers, preforms, electronics and speciality shapes L.C. Klein
  17. J. Appl. Phys. v.62 no.11 Structural and electrical properties of rf-sputtered amorphous barium titanate thin films K. Sreenivas;A. Mansingh
  18. J. Am. Ceram. Soc. v.72 no.8 Dependence of the crystal structure on particle size in barium titanate K. Uchino;E. Sadanaga;T. Hirose
  19. J. Kor Ceram. Soc. v.31 no.9 Effect of pyrochlore phase on electric properties for PNN-PT-PZ piezoelectric ceramics K.T. Lee;H.D. Nam
  20. Electroceramics A.J. Moulson;J.M. Herber