Microwave Dielectric Properties of $(Zr_{1-x}Sn_x)TiO_4$ Ceramics in the Response Surface Methodology

반응표면분석법에 의한 $(Zr_{1-x}Sn_x)TiO_4$계 교주파 유전 특성

  • Kim, Wang-Sup (Ceramin Processing Center, Korea Institute of Science and Technology) ;
  • Choi, Hwan (Ceramin Processing Center, Korea Institute of Science and Technology) ;
  • Moon, Myoung-Lib (Ceramin Processing Center, Korea Institute of Science and Technology) ;
  • Kim, Kyung-Yong (Ceramin Processing Center, Korea Institute of Science and Technology)
  • 김왕성 (한국과학기술연구원, 세라믹 공정센터) ;
  • 최환 (한국과학기술연구원, 세라믹 공정센터) ;
  • 문명립 (한국과학기술연구원, 세라믹 공정센터) ;
  • 김경용 (한국과학기술연구원, 세라믹 공정센터)
  • Published : 1995.05.01

Abstract

The effect of sintering temperature, sintering time and forming pressure on microwave dielectric properties of (Zr1-xSnx)TiO4 ceramics containing 1.0wt% B2O3, 0.3 wt% La2O3 and 1.0wt% NiTa2O6 was investigated using the response surface methodology. The optimum values of processing variables were determined based on the reproducibility. The optimum values of the dielectric constant of >35. Q.f0 of >55000 and $\tau$f=$\pm$5 ppm/$^{\circ}C$ could be obtained when the sample was pressed at 500~600kg/$\textrm{cm}^2$ and sintered at 1500~155$0^{\circ}C$ for 2~3 hrs.

Keywords

References

  1. Electronic Ceramics High Frequency Ceramic Dielectrics and their Application for Microwave Components W. Wersing;B.C.H. Steele(ed.)
  2. J. Am. Ceram. Soc. v.67 no.4 Microwave Characteristics of (Zr, Sn)T₁O₄ and BaO-PbO-Nd₂O₃-TiO₂ Dielectric Resonators K. Wakino;K. Minai;H. Tamura
  3. United States Patent no.4,665,041 Y. Higuchi;M.Katsube
  4. Proceedings of the First European Ceramics Society Conference v.Ⅱ no.2 Microwave Properties of ZrO₂-TiO₂-SnO₂ Ceramics D.M. Iddles;A.J. Bell;A.J. Moulson
  5. Annals of Mathmatical Stastics v.28 Multifactor Experimental Design for Exploring Response Surfaces G.E.P. Box;J.S. Hunter
  6. Technometrics v.21 Experiments with Mixture J.A. Cornell
  7. Technometrics v.5 Ridge Analysis of Response Surface Draper, N.R.
  8. Rubber Age v.89 Statistical Design of Experiments for Process Development of MBT S.A. Frenkel
  9. Proc. Inter. Conf. on Quality Control. Tokyo An Application of Response Surface Experiments to Control the Quality of Industrial Products: Model Fitting and Prediction of Responses S.H. Park
  10. IRE Tran. Microwave Theory Techn v.8 A Dielectric Resonator Method of Measuring Inductive Capacitance in the Millimeter Range B.W. Hakki;P.D. Coleman
  11. Institute of Electron & Communication Engineers of Japan v.72 no.33 Measurement of Complex Dielectric Constant by Columnar Dielectric Resonator Y. Kobayashi;S. Tanaka
  12. Korean Applied Physics v.4 no.3 A study on the Measurment for Electrical Characteristics of High Permittivity Dielectric Resonator at High Frequency Range K.Y. Kim;W.S. Kim;H. Choi;J.D. Kim
  13. The Korea Institute of Telematies and Electronics Study on the Microwave Dielectric Properties in the Dielectric Rod Resonator Method K.Y. Kim;W.S. Kim;H. Choi
  14. J. Am. Ceram. Soc. v.77 no.6 Effect of Sn Substitution on Cation Ordering in ($Zr_{1-x} Sn_x$)TiO₄ Microwave Dielectric Ceramics R. Christofferson;P.K. Davies;X. Wei