Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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A Study on the Synthesis of Organophilic Montmorillonite from Na-Montmorillonite and Octadecylenetrimethylammonium Ion and on itls Swelling Behavior

Na-Montmorillonite와 Octadecylenetrimethylammonium Ion에 의한 Organophilic Montmorillonite 층간화합물의 형성과 그 팽윤거동에 관한 연구

  • 조성준 (배재대학교 무기재료공학과)
  • Published : 1995.06.01
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Abstract

Octadecylenetrimethylammonium-montmorillonite as an organophilic montmorillonite intercalations complex was formed by cation exchange reaction between Na-montmorillonite and 9-octadecylenetrimethylammonium cation. After drying of this organophilic montmorillonite at $65^{\circ}C$ in high vacuum, the complexes were reacted with various swelling-solutions such as benzene, toluene, o-xylene, pyridine, $\alpha$-picoline, 2-ethyl-pyridine, 2-vinyl-pyridine and styrene, and the corresponding basal spacing obtained were 43.9$\AA$, 54.3$\AA$, 51.7$\AA$, 41.5$\AA$, 42.5$\AA$, 39.9$\AA$, 39.8$\AA$, 44.8$\AA$, respectively.

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References

  1. Angew Chem. v.75 no.113 Organische Derivate der Ghmmerartigen Schichtsilicate Armin Weiss
  2. Kolloid-Z. u. Z. Polymeere v.243 Anordnung und Orientierung Kationischer Tenside auf Silicatoberfl chen(Ⅳ. Anordnung von n-Alkylammoniumionen bei niederig Geladenen Schichtsilicaten) G. Lagaly;Armin Weiss
  3. Angew Chemie v.2 Aus der Chemie der Hochquellf Higen Tone (Bentorute) U. Hofmann
  4. Russian Chemical Reviews v.57 no.2 Layered Silicates as Catalysts M.I. Rozengart;G.M. Vyunova;G.V. Isagulyants
  5. Dissertation Studien $\"u$ber n-Alkylkomplexe von Montmorilloniten mit 3d-ubergangsmetalkationen und ber Katalytische Reaktionen von Oleylalkobol am Montmorilloniten Peter Brunner
  6. Diplonarbeit Beeinflussung der Sorption seigenschaften von Organophilierten Bentoniten K. Kuhn
  7. Schr. Angew Geol. Karlsruhe v.4 Untersuchungen zur Aufnahme von Losemitteln durch Organophilierte Bentonite K. Kuhn;A. Wesis
  8. Zusatzstoffe f$\"u$r Kunststoffe Dipl-Ing. Hans Domininghaus
  9. Mod. Plast. Encycl. Kaolin Clay Dawarth, A.J.
  10. Mod. Plast. Encycl. Fumed Coloidal Silica N.N.
  11. U.S. 3,251,869 Stearns T. Buntnam;Rhoads M. Speck;Cyrus A. Weisgerber
  12. U.S. 2,955,121 Latimer D. Myers;Charles G. Goebel;Fred O. Barrett
  13. U.S. 2,793,220 Fred O. Barrett;Charles C. Goebel;Robert M. Peters
  14. Angew. Chem. v.30 R$\"o$ntgenographische und Olloidchemische Untersuchung $\"u$ber Ton Ulrich Hofmann;Kurd Erndell;Diedrich Wilm