Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Synthesis of $\beta$-SiC Whiskers by Decomposition-Carbonization of Mullite

물라이트의 환원분해 및 탄화법에 의한 $\beta$-SiC 휘스커의 합성

  • 김종엽 (인하대학교 무기재료공학과) ;
  • 남원식 (인하대학교 무기재료공학과) ;
  • 최상욱 (인하대학교 무기재료공학과)
  • Published : 1995.10.01
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Abstract

$\beta$-SiC whiskers could be formed from a system of mullite-carbon-hydrogen by VLS mechanism at elevated temperatures. It was considered that methane gases were generated from the reaction of hydrogen gases with carbon black, and were reacted with mullite to produce two kinds of gases; silicon suboxide (SiO) and carbon monoxide (CO) of precursors of SiC. With increasing the synthesizing temperature up to 146$0^{\circ}C$, the formation of $\beta$-SiC whisker increased from 0.58 mg/$\textrm{cm}^2$ to 3.98 mg/$\textrm{cm}^2$ on the basis of unit area of carbon block, and the diameters of whiskers had their uniformity due to the reduction in stacking faults.

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References

  1. J. Am. Ceram. Soc. v.74 no.12 Inorganic Fiber-A Literature Review T.F. Cooke
  2. 요업재료의 과학과 기술 v.3 no.3 휘스커 강인화 세라믹 복합재료의 물성 강대갑;국일현
  3. J. Cryst. Growth v.1 no.5 Vapor-Liquid Solid and Melt-Growth Silicon Carbide C.E. Ryan;I. Berman;R.C. Marshall;D.P. Considine;J.J. Hawley
  4. J. Am. Ceram. Soc. v.52 no.11 Beta Silicon Carbide Whiskers prepared on a Molybdenum Substrate, Discussion and Notes N. Setaka;Z. Inoue
  5. J. Cryst. Growth v.9 The Growth of Silicon Carbide Needles by the Vapor-Liquid-solid Method I. Berman;C.E Ryan
  6. J. Ceram. Soc. Japan v.93 no.9 Growth of β-SiC Whiskers from Vapor Phase via Silicon Sulfide Inermediate M. Egashira;H. Katsukii;M. Mori;H. Kanteto;W. Kurahashi;S. Kawasumi
  7. J. Ceram. Soc. Japan. v.97 no.8 Synthesis of 2H-SiC Whiskers by Decomposition of Si₃N₄ J.B. Li;G. Peng;J.G. Wu;K. Koumoto
  8. J. Mater. Sci. v.27 Formation of SiC Whiskers form Silicon Nitride R.V. Krishnarao;M.M. Godkhindi
  9. J. Crist. Growth. v.87 no.2;3 Chemical Vapor Growth of β-SiC Whiskers form a Gas Mixture of $Si_6Cl_6$-H₂-Ar S. Motojima;M. Hasegawa
  10. J. Mater. Sci. v.21 no.7 The Formation of β-SiC Fibers with SiO₂-C-NaF(AIF₃) Components M. Kajiwara
  11. J. Mater. Sci. v.20 no.4 Growth of Beta-Silicon Carbide Whiskers by the VLS Process J.V. Milewski;F.D. Gac;J.J. Petrovic;S. R. Skaggs
  12. J. Ceram. Soc. Japan v.97 no.12 Growth Mechanism of SiC Whisker Synthesized from Silica and Carbon E. Maeda;T. Funahashi;R. Uchimura
  13. J. Cryst. Growth v.11 Growth of SiC Whisker in the System SiO₂-C-H₂ Nucleated by Iron G.A. Bootsma;W.F. Knippenberg;G. Verspui
  14. 인하대학교 석사학위논문 Y형 제오라이트 담지 니켈 촉배상에서 이산화탄소의 메탄화 반응 이관용
  15. Whisker - and Fiber - Toughned Ceramics in Proceedings of an International Conference Synthesis and Characterrization of VLS-Derived Silicon Carbide Whiskers P.D. Shalek;D.S. Phillips;D.E. Christiansen;J.D. Kartz;W.J. Parkinson;J.J. Pettrovic
  16. 耐火物 v.33 ムライトの 還元雰團氣下 ににおける 分解について 前佛 忠;南波安利;本 昇
  17. 耐火物 v.29 スライデイングイズル用 高 アルミナ 質 耐火物の 溶鋼に よる 寢食 に ついて 沖 和男;渡邊 高;川村 俊夫;相庭 吉郞
  18. Interceram v.2 The Influence of Various Gaseous Atmosphere on Refractories of the Al₂O₃-SiO₂-System, Part Ⅱ W. Kr$\"{o}$nert;H. Buhl
  19. J. Ceram. Soc. Japan. v.10 no.9 Synthesis of Si-O-C Fibers from Rice Husk Carbide K. Shimokawa;I. Sekiguchi;Y. Suzuki;Y. Ueda
  20. J. Ceram. Soc. Japan. v.99 Synthesis of β-SiC Powder and Formation of Stacking Faults W.S. Seo;C.H. Pai;K. Koumoto;H. Yanagita