향미성 Natto의 향기성분, 지방산 및 유기산 함량 분석

Flavor Component, Fatty Acid and Organic Acid of Natto with Spice Added

  • 김복란 (강원대학교 식품공학과) ;
  • 박창희 (샘표식품공업(주) 연구실) ;
  • 함승시 (강원대학교 식품공학과) ;
  • 이상영 (강원대학교 식품공학과)
  • 발행 : 1995.04.01

초록

Natto is a Japanese tradiational food made from whole soybeans by the fermentation of Bacillus natto. This study was attempted to improve the taste of Natto, garlic(2%) and red pepper oleoresin(0.2%) were added. Conventional Natto(N-1), garlic Natto(N-2), red pepper oleoresin Natto(N-3), garlic and red pepper oleoresin Natto(N-4) were prepared. Volatile flavor components, fatty acid, organic acid, pH and titratable acdity in all samples were investigated. The experimental results revealed the presence of 62 volatile components in conventional Natto. Among there, the major flavor compounds were identified to be 2, 5-dimethylpyrazine, trimethyl-pyrazine, 2, 6-bis91, 1-dimethylethyl) phenol. Seventy-one volatile compounds were detected in N-2, and major compounds were identified to be methyl-2-propenyl disulfide, 2, 6-bis(1, 1-dimethylethyl)phenol and 2, 5-dimethylpyrazine. The amounts of volatile compounds, 2-methyoxyphenol and 1, 2-benzenedicarboxylic acid increased by addition of garlic, where as, 1,2 -propanediol, 1-hexanol and 2, 5-dimethylpyrazine decreased. The compounds, 4, 5-dihydroxy-5-propyl-1H-pyrazole, 1, 1, 3-trimethylcyclopentane were identified in N-3. The compounds, such as trimethylpyrazine, 3-ethyl-2,5-dimethylpyrazine increased by addition of red pepper oleoresin, whereas 1,2-propanediol, 1-hexanol and 2,5-dimethylpyrazine decreased. Fatty acid compositions were mainly consisted of linoleic acid(43.66~55.89%) and followed by oleic, palmitic, linolenic, stearic, arachidic, myristic acid. The organic acids we4re identified to be citric(28.2~30.6), acetic(50.0~73.3) and pyroglutamic acid(2.1~3.7).

키워드

참고문헌

  1. 과연휘보 v.4 Natto 및 가열대두의 영양학적 고찰 정태석;계성렬;윤두선
  2. 과연휘보 v.1 대두식품의 효소화학적 연구(제1보) 정태석
  3. 농화학회지 v.8 Natto 제조중의 단백질, peptide 및 amino acid의 변화에 관한 연구 김수영;김재욱
  4. 한국농화학회지 v.35 청국장 발효중 점질성 고분자 물질의 생성에 관한 연구 이용림;김성호;정낙현;임무현
  5. 한국식품과학회지 v.23 청국장 점질물의 이화학적 특성 이부용;김동만;김길환
  6. Experientia v.43 A novel fibrinolytic enzyme(Nattokinase) in the vegetablel cheese Natto : A typical and popular soybean food in the Japanese diet Sumi,H.;Hamada,H.;Tsushima,H.;Mihara,H.;Muraki,H.
  7. 調味料, 香辛料의 事典 福場博保;小林彰夫
  8. J. Food Sci. v.37 Oxidative decoloration of betacarotene in low-moisture model system Chou,H.E.;Breene,W.M.
  9. 한국영양식량학회지 v.24 향미성 Natto 제조과정 중 당류 및 아미노산 함량 변화 김복란;박창회;윤복만;정민철;이상영
  10. J. Agric. Food Chem. v.25 Isolation of volatile componets from a model system Schultz,T.H.;Flath,R.A.;Mon,T.R.;Eggling,S.B.;Teranishi,R.
  11. Anal. Chem. v.38 Rapid preparation of fatty acid esters from lipids for gas chromatographic analysis Metcalfe,L.D.;Schmitz,A.A.;Pelka,J.R.
  12. 全國 Miso 分析法 全國Miso技術會編
  13. Agric. Biol. Chem. v.49 Comparison of compositions of odor components of natto and cooked soybean Sugawara,E.;Ito,T.;Odagira,S.;Kuboda,K.;Kobayashi,A.
  14. 한국식품과학회지 v.21 청국장 숙성중의 향기성분 변화 최성희;지영애
  15. 중앙대학교 박사학위논문 청국장 메주 발효 과정중의 화학성분 및 숙성중 Alkylpyrazine류의 변화 복진영
  16. 한국영양식량학회지 v.21 재래식 메주및 된장의 향기성분 김경업;김미혜;최병대;김태수;이종호
  17. Food Chemistry v.7 Changes in volatile flavor components of soybeans during roasting Kato,T.;Doi,Y.;Tsugita,T.;Kosai,K.;Kamiya,T.;Kurata,T.
  18. Spice v.142 Heterocyclic flavoring and aroma coma compounds, a pyrazine in food. An update(Ⅱ) Mastukura,T.
  19. Agric. Biol. Chem. v.44 Change of headspace volatile compounents of soybeans during roasting Doi,Y.;Tsugita,T.;Kunata,T.;Kato,H.
  20. 한국식품과학회지 v.22 마늘 정유물의 항기성분 및 저장 안정성 조길석;김현구;하재호;박무현;신효선
  21. Rep. Natl. Food. Inst. v.43 Lipid content and fatty acid composition of Natto Taira,H.;Suzuki,N.
  22. 농산식품가공 김재근
  23. Nippon Shokuhin Kogyo Gakkaish v.34 Change in the volatile components of Natto during manufacturing and storage Kanno,A.;Takamatsu,H.
  24. Rep. Natl. Food. Inst. v.51 Citrate-lyase of natto bacteria Kiuchi,K.;Yamamoto,K.;Hunane,K.;Mori,Y.