Acid and Base Properties of Chemical-Treated Natural Zeolite

  • Published : 1995.08.01

Abstract

To study the acid and base properties of chemical-treated natural zeolite, FT-IR analysis was performed by the adsorption of pyridne and pyrrole and thermo-gravimetric analysis was done by the adsorption of NH$_{3}$. These solid catalysts have two acid sites, which are related to the Bronsted and Lewis acid sites, respectively. HIC-treatment led to the increased acidity and the maintained basicity.Acidity of NaHO-treatment samples also increased with thr NaOH-treatment but basicity decreased. The p-xylene selectivity on the chemical-treatment zelite was higher than that on the untreated zeolite.

Keywords

References

  1. Zeolite Catalysis : Principles and Applications v.164 B.Subhash
  2. Catalytic Chemistry C.G.Bruce
  3. Molecular Sieves : Principles of Synthesis and Identification R. Szostak
  4. J. Korean Institute of Surf. Eng. v.26 J.Y. Lee;H.K. Lee:J.S. Lee;M.J. Shim;S.W. Kim
  5. J. Catal. v.25 J. Freel
  6. J. Catal. v.28 K.A. Becker;H.G. Karge;W.D. Streubel
  7. J. Catal. v.76 L.B. Young;S.A. Butter;W.W. Kaeding
  8. J. Am. Chem. Soc. v.82 R.H. Allen
  9. J. Phys. Chem. v.68 A.J. Silvestri;C.D. Prater
  10. J. Catal. v.98 T. Inui;H. Matsuda;O. Yamase:H. Nagata;K. Fukuda;T. Ukawa;A. Mitamoto
  11. Ind. Eng. Chem. Prod. Dev. v.20 S.B. Shashldhar;R. Patwardhan
  12. J. Catal. v.51 A. Cortes;A. Corma
  13. J. Korean Ind. & Eng. Chem. v.5 J.Y. Lee;M.J. Shim;S.W. Kim