Study on $CdIn_{2}Te_{4}$ single crystal growth and electrical characteristics

$CdIn_{2}Te_{4}$ 단결정 성장과 전기적 특성

  • Published : 1996.03.01

Abstract

A $CdIn_{2}Te_{4}$ single crystal was grown by modified veritical bridgman method. The $CdIn_{2}Te_{4}$ single crystal was evaluated to be tetragonal by the powder method. The $CdIn_{2}Te_{4}$ single crystal was confirmed to be grown with its c axis along the lengthe of the boule by the Laue reflection method. Hall effect of $CdIn_{2}Te_{4}$ single crystal was estimated by van der pauw method from 293 K to 30 K. Hall data of the sample perpendicular to c axis was $n=8.75{\times}10^{23}electrons/m^{3},\;R_{H}=7.14{\times}10^{-5}m^{3}/C,\;{\sigma}=176.40{\omega}^{-1}m^{-1},\;{$\mu}=3.41{\times}10^{-2}m^{2}/V.s$ and the sample parallel to c axis was $n=8.61{\times}10^{23}electrons/m^{3},\;R_{H}=7.26{\times}10^{-5}m^{3}/C,\;{\sigma}=333.38{\omega}^{-1}m^{-1}\;and\;{$\mu}=2.42{\times}10^{-2}m^{2}/V.s$ for room temperature. The value of Hall coefficient on sample perpendicular or parallel to c axis were positive. There $CdIn_{2}Te_{4}$ single crystal was p-type semiconductor.

$CdIn_{2}Te_{4}$ 단결정을 Bridgman방법으로 성장하였다. 성장된 $CdIn_{2}Te_{4}$ 단결정은 분말법으로 X-ray diffraction을 측정하여 tetragonal로 성장되었음을 알 수 있었고 격자상수는 Nelson-Riley 보정식을 이용하여 외삽법으로 구한 결과 $a_{0}$$6.215{\AA}$, $c_{0}$$12.390{\AA}$이었다. $CdIn_{2}Te_{4}$ 결정이 단결정임을 알아보기 위해 Laue 배면 반사법으로 측정하였는데 c축에 수평한면은 (110), c축에 수직한 면은 (001)으로 성장되었음을 알 수 있었다. 또한 van der Pauw방법으로 Hall 효과를 측정하여 운반자 농도와 이동도를 구하였으며, c축에 수직한 시료의 carrier density는 $8.75{\times}10^{23}electrons/m^{3},\;mobility는\;3.41{\times}10^{-2}m^{2}/V.s$였으며 c축에 평행한 시료의 carrier density는 $8.61{\times}10^{23}electrons/m^{3},\;mobility는\;2.42{\times}10^{-2}m^{2}/V.s$였다. 또한 Hall 계수가 양의 값이여서 $CdIn_{2}Te_{4}$ 단결정은 p형 반도체임을 알 수 있었다.

Keywords

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