Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Ferroelectric Domans in $BaTiO_3$

$BaTiO_3$의 강유전성 분역

  • 박봉모 (서울대학교 무기재료공학과) ;
  • 정수진 (서울대학교 무기재료공학과)
  • Published : 1996.01.01
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Abstract

A large amount of papers about the cubic-to-tetragonal phase transition the ferroelectric domain structures of the BaTiO3 were already reported but there exist still some needs to observe the domain behaviors directly. In this study the domain structures of the tinned plates prepared from ta single crystal grown by the TSSG technique were observed using a polarizing microscope TE and X-ray topography. The spatial relation be-tween the orientation states of domains was investigated and the effects of external stresses and electric fields on the behaviors of ferroelectric and ferroelastic domains were studied. All the 90$^{\circ}$walls cut off in the crystal are the wedge shaped lamellar domains and all the straight boundaries in the observed domain patte군 can be interpreted as the head-to-tail 90$^{\circ}$walls. The irregular overlapped boundaries commonly observed by using a polarizing microscope and X-ray topography are complex combinations of well-known 90$^{\circ}$walls and are domain walls were predominant and were stabilized after surface polishing. In the paraelectric phase region the domain walls vanished but the residual surface strain patterns could be seen at the same positions of the stabilized 90$^{\circ}$a-a walls in the tetragonal phase region, These stabilized walls resulted from the surface strain had a memory effect in domain formation during the repeated phase transitions and could notr be affected by an external electtric field.

Keywords

References

  1. Phys. Rev. v.76 no.8 Domain Structure and Phase Transitions in Barium Titanate P.W. Forsbergh
  2. Phys. Rev. v.95 no.3 Domain Formation and Domain Wall Motions in Ferroelectric BaTiO₃Single Crystals W.J. Merz
  3. Phys. Rev. v.88 Domain Properties on Barium Titanate W.J. Merz
  4. Phys. Rev. v.98 Etch Patterns and Ferroelectric Domains in BaTiO₃Single Crystals J.A. Hooton;W.J. Merz
  5. J. Am. Ceram. Soc. v.69 no.8 Scanning Electron Microscopy and Transmission Electron Microscopy Study of Ferroelectric Domains in Doped BaTiO₃ Y. Hu;H.M Chan;Z.X. Wen;M.P. Harmer
  6. J. Am. Ceram. Soc. v.55 no.1 Nature of Aging in Ferroelectric Ceramics G.H. Jonker
  7. Ferroelectrics v.4 Stabilization Effects in Piezoelectirc Lead Titanate Zirconate Ceramics H. Thomann
  8. Ferroelectrics v.22 Ferroelectric Domain Stabilization in BaTiO₃by Bulk Ordering of Defects P.V. Lambeck;G.H. Jonker
  9. J Phys C, Solid State Phys. v.11 Loss Mechanisms and Domain Stabilization in Doped BaTiO₃ H.J. Hagemann
  10. J. Phys. Chem. Solids v.47 no.5 The Nature of Domain Stabilization in Ferroelectric Perovskites P.V. Lambeck;G.H. Jonker
  11. Japan. J. Appl. Phys. v.31 no.9B Space Charge Effects on Ferroelectric Ceramic Particle Surfaces K. Okazaki;H. Maiwa
  12. BaTiO₃세라믹스의 분역구조에 관한 연구 김상범
  13. Acta Cryst. v.A46 Growth of RIG(R=Y, Sm, Ho, Nd) and BaTiO₃Single Crystals from High Temperature Solutions S.H. Lee;B.M. Park;H.M. Park;S.J. Chung
  14. 한국결정학회지 v.3 no.2 TSSG 법에 의한 BaTiO₃단결정 육성 박봉모;정수진
  15. Phys. Rev. v.76 no.6 The Electric and Optcal Behavior of BaTiO₃Single-Domain Crystals W.J. Merz
  16. Phys. Rev. v.73 Domain Structure and Dielectric Response of Barium Titanate Single Crystals B. Matthias;A. von Hippel
  17. J Phys Soc. Jpn. v.17 Electron Optical Studies of Barjum Titanate Single Crystal Films M. Tanaka;M. Kitamura;G. Honjo
  18. J Phys. Soc. Jpn. v.19 Eletron Optical Studies of Barium Titanate Single Crystal Films M. Tanaka;G. Honjo
  19. Phys. Stat Sol. v.4 Electron Microscope Transmission Images of Coherent Domain Boundaries (Ⅰ) R. Gevers;P. Delavignette;H. Blank;S. Amelinckx
  20. Phys. Stat Sol. v.5 Electron Microscope Transmission Images of Coherent Domain Boundaries (Ⅱ) R. Gevers;P. Delavignette;H. Blank;J. Van Landuyt;S. Amelinckx
  21. J Am Ceram. Soc. v.52 no.4 Aging in Tetragonal Ferroelectric Barium Titanate R.C. Bradt;G.S. Ansell
  22. Principles and Applications of Ferroelectrics and Related Materials M.E. Lines;A.M. Glass
  23. J. Am. Ceram. Soc. v.77 no.12 Optical Electron Microscopic and X-ray Topographic Studies of Ferroic Domain in Baium Titanate Crystals Grown from High Temperature Solution B.M. Park;S.J. Chung
  24. J. Am Ceram Soc. v.39 Domain Twinning in Barium Titanate Ceramics W.R. Cook Jr
  25. J. Am. Ceram. Soc. v.40 no.6 Microstructure of Barium Titanate Ceramics R.C. DeVries;J.E. Burke
  26. J Appl. Phys. v.51 no.9 Domain Configuration and Equilibrium Size of Domains in BaTiO₃Ceramics G. Arlt;P. Sasko
  27. J Mat. Sci. v.25 Twinning in Ferroelectric and Ferroelastic Ceramics: Stress Relief G. Arlt
  28. Ferroelectrics v.157 Domain Comfigurations in BaTiO₃Single Crystals Grown from High Temperature Solution B.M. Park;S.J. Chung
  29. Phys. Rev. v.155 Paraelectric-Ferroelectric Phase Boundaries in Semiconducting Perovskite-Type Crystals M. Didomenico Jr;S.H. Wemple
  30. New Ceramics v.5 Technique for preparation of BaTiO₃single crystal A. Kurosaka
  31. J. Eurv. Ceram. Soc. v.12 Effect of External Compressive Stress on the Domain Configuration of Barium Titanate Ceramics S.B. Kim;T.J. Chung;D.Y. Kim
  32. Phys. Stat Sol. (a) v.49 Optical Investigation of the Cubic-Tetragonal Phase Transition in BaTiO₃Single Crystals H.E. Muser;W. Kuhn;J. Albers