The Fabrication and Their Properties of Zirconia-spinel COmposites by Reaction Sintering

반응소결에 의한 지르코니아-스피넬 복합체의 제조 및 성질

  • 황규홍 (경상대학교 무기재료공학과 /첨단소재연구소) ;
  • 김상모 (경상대학교 무기재료공학과 /첨단소재연구소)
  • Published : 1996.07.01

Abstract

The spinel/cubic stabilized zirconia composites were fabricated via, The reaction sintering of monoclinic zirco-nia(baddeleyite) added with MgAl powder. During heating Mg and Al were oxidizedfirst and subsequently the oxides formed spinel (MgAl2O4) and finally remained MgO stabilized the zirconia, Because the oxides formed during the oxidation process would have very fine grain size (order of submicron) mainly due to the effects of attrition milling the reaction sintering was more effective in densification and improvement of strength and fracture toughness than conventional sintering with direct addition of MgO. The sintering behavior phase transformation during firing and mechanical properties of sintered body were investigated with emphasis on the relations between spinel formation due to MgAl addition and sintering and mechanical properties.

Keywords

References

  1. Structural Ceramics of Treatise on Materials Science and Technology v.29 Transformation Toughened Ceramics for Structural Applications W.R. Cannon;J.B. Wachtman Jr.(ed.)
  2. US Patent 4,279,655 Partially Stabilized Zirconia R.C.Garvie(et al.)
  3. J. Kor. Ceram. Soc v.29 no.6 Fabrication of Low-Shrinkage Reaction-Bonded Alumina Ceramics J.H. Park(et al)
  4. J. Am. Cram. Soc v.73 no.9 Influence of Magnesium-Aluminum Spinel on the Directed Oxidation of Molten Aluminum Alloys M. Sindel(et al)
  5. 한국요업학회지 v.31 no.4 산화물과 금속 복합분말의 attrition milling및 반응소결.Ⅱ;분말의 분쇄특성에 따른 반응 소결 거동 황규홍;김의훈
  6. Sintering and Matcrials Sintering Behavior and Mechanical Properties of Reaction-Sintered Zirconia/Spinel Composites Kyu Hong Hwang(et al);Li Nan(ed.)
  7. Phd. Thesis Effect of ZrO₂Addition and Nonstoichiometry on Sintering and Physical Properties of Magnesium Aluminate Spinel JuYoung Kim
  8. Phd.Thesis v.66 no.5 The Influence of Thermal Decomposition on the Mechanical Properties of Magnesia-Stabilized Cubic Zirconia M.V. Swain;R.C. Garvie;R.H.J. Hannink
  9. Fracture Mechanics of Ceramics v.5 Indentation Fracture Toughness of Brittle Materials for Palmqvist Cracks K. Niihara(et al);R.C. Bradt(et al.)(ed.)
  10. Fracture Mechanics of Ceramics v.6 A Statistical Analysis of Crack Deflection as a Toughening Mechanism in Ceramic Material K.T.Faber(et al);R.C.Bradt(et al.)(ed.)
  11. J. Am. Ceam. Soc. v.62 no.7;8 Hardness, Toughness and Brittleness. An Indentation Analysis B.R. Lawn(et al)