Densification of Carbon/Carbon Composites by Pulse CVI with and without Residence

펄스화학기상침트법에 의한 탄소/탄소 복합재료의 치밀화에 있어서 가스유지시간 유무의 영향

  • 이용근 (한국화학연구소 무기소재부) ;
  • 류호진 (한국화학연구소 무기소재부) ;
  • 박희동 (한국화학연구소 무기소재부)
  • Published : 1996.08.01

Abstract

Two-dimensional carbon/carbon preforms made of PAN-based carbon yarn and phenolic resin were densified with pyrolysis of propane by pulse chemical vapor infiltration where repeated the cycle of gas introduction residence and evacuation. Maximim density increment was 14% when infiltration temperature and time were 100$0^{\circ}C$ and 21.25 hrs respectively. The distribution of deposits of pyrocarbon by this process has been occurred uniformly in the bottom middle and top of carbon/carbon composite preform Pulse CVI with residence is most effective in increasing density and shortening infiltration time among isothermal CVI and pulse CVI with and without residence.

Keywords

References

  1. Ceram. Eng. Sic. Proc. v.10 no.7-8 Review,status, and future of the chemical vapor infiltration process for fabrication of fiberreinforced ceramic composites W.J. Lackey
  2. J. Electrochem. Soc. v.136 no.2 Densification of porous materials by chemical vapor infiltration S.M. Gupte;J.A. Tsamopoulos
  3. Carbon v.23 no.6 Carbon/carbon composites prepared by chemical vapor deposition S. Marinkovic;S. Dimitrijevic
  4. Am. Ceram. Soc. Bull. v.65 no.2 Synthesis of fiber-reinforced SiC composites by chemical vapor infiltration D.P. Stinton;A.J. caputo;R.A. Lowden
  5. J. Am. Ceram. Soc. v.77 no.3 Effects of deposition mechanisms in the modeling of forced-flow/temperature-gradient chemical vapor infiltration N.H. Tai;R.W. Chou;C.C.M. Ma
  6. Ceram. Eng. Sci. Proc. v.9 no.7-8 Deposition kinetics in forced flow/thermal gradient CVI T.L. Starr
  7. J. Mater. Sci. v.29 Pulse chemical vapour deposition and infiltration of pyrocarbon in model pores with rectangular cross-section, Part II. Study of the infiltration P. Dupel;R. Pailler;X. Bourrat;R. Naslain
  8. J. Mater. Sci. v.27 Pulsed chemical vapour infiltration of SiC to three-dimensional carbon fibre preforms K. Itoh;M. Imuta;A. Sakai;J. Gotoh;K. Sugiyama
  9. J. Mater. Sci. v.24 Reinforcement and antioxidizing of porous carbon by pulse CVI of SiC K. Sugiyama;E. Yamamoto
  10. J. Mater. Sci. v.25 Pulsed chemical vapour infiltration of SiC in porous carbon or SiC particulate preform using and r.f. heating system K. Sugiyama;Y. Ohzawa
  11. Carbon v.34 no.3 Densification of carbon/carbon composites by chemical vapor infiltration H.J. Jeong;H.D. Park;J.D. Lee;J.O. Park
  12. Carbon v.33 no.9 Structure of pyrocarbon infiltrated by pulse CVI P. Dupel;X. Bourrat;R. Pailler