Sintering and Electrical Characteristics of Semiconducting $BaTiO_3$ Ceramics with Addition of $BaB_2O_4$

$BaB_2B_4$ 첨가에 따른 반도성 $BaTiO_3$ 세라믹스의 소결 및 전기적 특성

  • 허영우 (경북대학교 무기재료공학과) ;
  • 이준형 (경북대학교 무기재료공학과) ;
  • 김정주 (경북대학교 무기재료공학과) ;
  • 김남경 (경북대학교 무기재료공학과) ;
  • 조상희 (경북대학교 무기재료공학과)
  • Published : 1996.09.01

Abstract

The variations of sintering and electrical characteristics of semiconducting BaTiO3 ceramics with sintering agents added were investigated comparing the case of BaB2O4 addition to BN and TiO2 addition. When BaB2O4 added in BaTiO3 ceramics the densitifcation of specimen could be acheived more easily and recvealed the better PTCR characteristics than BN and TiO2 addition. As increase of addition of BaB2O4 in BaTiO3 spec imens the slope of resistivity jump also increased but the temperature of maximum resistivity decreased, It was supposed that addition of BaB2O4 led to increase of Ns (acceptor state density) value at grain boundaries.

Keywords

References

  1. Ceram. Bull v.47 no.3 Semiconducting BaTiO₃with Additives of Al₂O?, SiO₂and TiO₂ Y. Matsuo;M. Fujimura;H. Sasaki;K. Nagase;S. Hayakawa
  2. J. Appl. Phys v.66 no.3 Effect of Sintering Aids on the Electrical Properties of Positive Temparature Coefficient of Resistivity BaTiO₃Ceramics H.F. Cheng
  3. J. Am. Ceram. Soc v.75 no.1 A Novel Method for the Uniform Incorporation of Grain Boundary Layer Modifiers in Positive Temperature Coefficient of Resistivity Barium Titanate V. Ravi;T.R.N. Kutty
  4. J. Am. Ceram. Soc v.70 no.1 Control of Liquid-Phase-Enhanced Discontinuous Grain Growth in Barium Titanate D.F.K. Hennings;R. Janssen;P.J.L. Reynen
  5. J. Am. Ceram. Soc v.68 no.11 Effect of Ba:Ti Ratio on Densification of LiF-Fluxed BaTiO₃ D.A. Tolino;J.B. Blum
  6. J. Am. Ceram. Soc v.69 no.8 Reaction During of Barium Titanate with Lithium Fluoride J.P. Guha;H.U. Anderson
  7. Yogyo-Kyokai-shi v.93 no.5 Sintering of Semiconducting BaTiO₃Doped with Si₃N₄ N. Yamamoto;O. Kamigaito
  8. J. Kor. Ceram. Soc v.31 no.10 반도성 BaTiO₃ 세라믹스의 미세구조및 PTCR 특성에 미치는 Si₃N₄ 첨가효과 김준수;정윤해;이병하
  9. J. Jap. Ceram. Soc v.97 no.10 Influence of the Addition of BN and Bi₂O₃ on the Microstructure and the PTCR Effect in High-Curie-Point Barium-Lead Titanate Ceramic Y. Kato;M. Takeo;R.T. Liang;M. Kuwabara
  10. J. Am. Ceram. Soc v.77 no.3 Semiconducting Barium Titanate Ceramics Prepared by Boron-Containing Liquid-Phase Sintering In-Chyuan Ho
  11. Ceramic Transactions Grain-boundary-Controlled Properties of Fine Ceramics Effect of BN addition on the Sintering and Electrical Properties of Y-doped BaTiO₃Ceramics Seh-Jin Park;Joon-Hyung Lee;Sang-Hee Cho
  12. J. Am. Ceram. Soc. v.38 no.11 BaTiO₃-SiO₂ Phase Diagram D.E. Rose;R. Roy
  13. J. Am. Ceram. Soc v.54 no.9 Exaggerated Grain Growth in Liquid-Phase Sintering of BaTiO₃ Y. Matsuo;H. Sasaki
  14. Powder Diffraction File, Card No. 24-86
  15. Phase Diagrams for Ceramists v.3 BaB₂O₄-BaTiO₃Phase Diagram Y. Goto;L.E. Cross
  16. Mater. Res. Bull v.2 Halogen Treatment of Barium Titanate Semiconductors G.H. Jonker
  17. J. Am. Ceram. Soc v.75 no.3 Experimental Evaluation of the Acceptor States Compensation in Positive Temperrature Coefficient Type Barium Titanate B. Huybrechts;K. Ishizaki;M. Takata