High-Temperature Oxidation of MoSi2 Heating Elements

이규화몰리브덴 고온발열체의 고온산화거동

  • 서창열 (한국자원연구소 자원활용.소재연구부) ;
  • 장대가 (한국자원연구소 자원활용.소재연구부) ;
  • 심건주 (한국자원연구소 자원활용.소재연구부) ;
  • 조덕호 (대전산업대학교 금속공학과) ;
  • 김원백 (한국자원연구소 자원활용.소재연구부)
  • Published : 1996.01.01

Abstract

MoSi2 heating elements were fabricated by sintering of MoSi2 powders which were synthesized through SHS(Self-propagating high-temperature synthesis). Their high-temperature oxidation behavior in air through SHS(Self-propagating high-temperature synthesis). Their high-temperature oxidation behavior on air at 1000-1600$^{\circ}C$ was investigated through a high-temperature X-ray diffractomer and isothermal heating in a muffle furnace. The thermal expansion of MoSi2 and SiO2 was studied by measuring their lattice parameters on heating. The linear expansion coeffcient of MoSi2 along c-axis was about 1.5 times larger than that along a-axis showing a strong thermal anisotropy. Few $\mu\textrm{m}$-thick Mo5Si3 layer was found beneath SiO2 layer suggesting that The major reaction products would be SiO2 and Mo5Si3. The Si-rich bentonite resulted in the faster growth of MoSi2 grains probably by enhancing the mass transport when they are melted during high-temperature oxidation.

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References

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