Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Selective Acylation and Aminomethylation of Benzoylated Calix[4]arene

  • Published : 1996.06.20
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Abstract

Two different acyl substituents were introduced at the lower rim of calix[4]arene by the two step reactions. Calix[4]arenes (1) reacted with 3,5-dinitrobenzoyl chloride to yield monosubstituted calix[4]arene (2). Second substitution was achieved by the reaction of 2 with various acyl chlorides. Aminomethylation of monobenzoylated calix[4]arene was conducted successfully in the presence of secondary amine and formaldehyde.

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References

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