대한화학회지 (Journal of the Korean Chemical Society)

  • 제40권8호
  • /
  • Pages.565-570
  • /
  • 1996
  • /
  • 1017-2548(pISSN)
  • /
  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지

4'-[N-(9-Acridinyl)]-1'-(N-methanesulfonyl)-3'-methoxyquinonediimide에 대한 Thiophenol 유도체의 친핵성 첨가물의 합성에 관한 연구

Synthetic Studies on the Nucleophilic Adducts of Thiophenol Derivatives to 4'-[N-(9-Acridinyl)]-1'-(N-methanesulfonyl)-3'-methoxyquinonediimide

  • 김태린 (고려대학교 화학과) ;
  • 정동인 (한국산업안전공단 산업보건연구원) ;
  • 편상용 (부경대학교 화학과)
  • Kim, Tae Rin (Department of Chemistry, Korea University) ;
  • Chung, Dong In (Industrial Health Research Institute Korea Industrial Safety Corporation) ;
  • Pyun, Sang Yong (Department of Chemistry, Pukyung National University)
  • 발행 : 19960800
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초록

4'-[N-(9-acridinyl)]-1'-(N-methanesulfonyl)-3'-methoxyquinonediimide(AMQD, 5)를 간편하고 효율적인 새로운 방법으로 얻었으며, AMQD에 thiophenol 유도체를 반응시켜 6종류의 새로운 첨가 생성물(6a-6f)들을 합성하였다. 이 화합물들의 구조는 원소분석, Mass, IR 및 NMR 스펙트라 등에 의하여 확인되었다.

A simple and efficient new synthetic method of 4'-[N-(9-acridinyl)]-1'-(N-methanesulfonyl)-3'-methoxyquinonediimide(AMQD, 5) was developed and six new nucleophilic adducts(6a-6f) were prepared by the addition of thiophenol derivatives to AMQD. The structures of these compounds were confirmed by elemental analysis, mass, ir and nmr spectra.

키워드

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