The Substrate Effects on Kinetics and Mechanism of Solid-Phase Crystallization of Amorphous Silicon Thin Films

  • Published : 1997.04.30

Abstract

The substrate effects on solid-phase crystallization of amorphous silicon (a-Si) films deposited by low-pressure chemical vapor deposition (LPCVD) using $Si_2H_6$ gas have been extensively investigated. The a-Si films were prepared on various substrates, such as thermally oxidized Si wafer ($SiO_2$/Si), quartz and LPCVD-oxide, and annealed at 600$^{\circ}C$ in an $N_2$ ambient for crystallization. The crystallization behavior was found to be strongly dependent on the substrate even though all the silicon films were deposited in amorphous phase. It was first observed that crystallization in a-Si films deposited on the $SiO_2$/Si starts from the interface between the a-Si and the substrate, so called interface-interface-induced crystallization, while random nucleation process dominates on the other substrates. The different kinetics and mechanism of solid-phase crystallization is attributed to the structural disorderness of a-Si films, which is strongly affected by the surface roughness of the substrates.

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References

  1. J. Appl. Phys. v.75 no.7 Polycrystalline silicon thin films processed with silicon ion implantation and subsequent solid-phase crystallization: Theory, experiments and thin-film transistor applications Yamauchi, N.;Reif, R.
  2. IEEE Electron Device Lett. v.8 no.8 High-performance thin-film transistors in low-temperature crystallized LPCVD amorphous silicon films Hatalis, M.K.;Greve, D.W.
  3. J. Appl. Phys. v.69 no.3 Recrystallization amorphous silicon films deposited by low-pressure chemical vapor deposition rom $Si_2H_6$ gas Nakazawa, K.
  4. J. Appl. Phys. v.77 no.5 Structure and grain boundary defects of recrystallized silicon films prepared from amorphous silicon deposited using disilane Hasegawa, S.;Watanabe, S.;Inokura, T.;Kurata, Y.
  5. Jpn. J. Appl. Phys. v.31 no.2A Axially controlled solid-phase crystallization of amorphous silicon Hasegawa, S.;Nakamura, T.;Kurata, Y.
  6. J. Appl. Phys. v.71 no.11 Structure and crystallization of low-pressure chemical vapor deposited silicon films using $Si_2H_6$ gas Hong, C.H.;Park, C.Y.;Kim, H.J.
  7. Appl. Phys. Lett. v.40 no.6 Critical volume fraction of crystallinity for conductivity percolation in phosphorus-doped Si:F:H alloys Tsu, R.;Hernandez, J.G.;Chao, S.S.;Lee, S.C.;Tanaka, K.
  8. Solid-state phase transformations;Treatise on Solid State Chemistry, vol.5 Raghavan, V.;Cohen, M.;Hannay, N.B.(ed.)
  9. J. Appl. Phys. v.62 no.5 Recrystallization of amophized polycrystalline silicon films on $SiO_2:$ Temperature dependence of the crystallization parameters Iverson, R.B.;Reif, R.
  10. J. Appl. Phys. v.66 no.9 Analysis of solid phase crystallization in amorphized polycrystalline Si films on quartz substrates Nakamura, A.;Emoto, F.;Fujii, E.;Yamamoto, A.;Uemoto, Y.;Senda, K.;Kano, G.
  11. J. Appl. Phys. v.77 no.1 High-resolution transmission electron microscopy study of solid phase crystallized silicon thin films on $SiO_2:$ Crystal growth and defects formation Kim, J.H.;Lee, J.Y.;Nam, K.S.
  12. J. Elec. Mat. v.23 no.3 Structural chracteristics of as-deposited and crystallized mixed-phse silicon films Voutsas, A.T.;Hatalis, M.K.