Sesquiterpene Components from the Flower Buds of Magnolia fargesii

  • Jung, Keun-Young (Natural Products Biosynthesis Research Unit, Korea Research Institute of Bioscience and Biotechnology) ;
  • Kim, Dong-Seon (Natural Products Biosynthesis Research Unit, Korea Research Institute of Bioscience and Biotechnology) ;
  • Oh, Sei-Ryang (Natural Products Biosynthesis Research Unit, Korea Research Institute of Bioscience and Biotechnology) ;
  • Lee, Im-Seon (Natural Products Biosynthesis Research Unit, Korea Research Institute of Bioscience and Biotechnology) ;
  • Lee, Jung-Joon (Natural Products Biosynthesis Research Unit, Korea Research Institute of Bioscience and Biotechnology) ;
  • Lee, Hyeong-Kyu (Natural Products Biosynthesis Research Unit, Korea Research Institute of Bioscience and Biotechnology) ;
  • Shin, Dong-Hyuk (Dong-Wha Pharm. Ind. Co.) ;
  • Kim, Eun-Hee (Magnetic Resonance Group, Korea Basic Science Institute) ;
  • Cheong, Chae-Joon (Magnetic Resonance Group, Korea Basic Science Institute)
  • Published : 1997.08.01

Abstract

From the Chinese crude drug shin-i, the flower buds of Magnolia fargesii, four sesquiterpene, oplopanoe (1), oplodiol (2), homalomenol A (3) and $1{\beta},4{\beta},7{\alpha}$-trihydroxyeudesmane (4) were isolated. These structures were elucidated and the ${13}^C-NMR$ chemical shifts of these compounds were revised by means of various 2D-NMR techniques.

Keywords

References

  1. Phytochemistry v.23 A hydroxygermacrene and other constituents from Pseudobrickellia brasiliensis Bohlmann,F.;Zdero,C.;King,R.M.;Robinson,H.
  2. Planta Med. v.54 On the $Ca^++$-antagonistic principles of the flower bubs of Magnolia fargesii Chen,C.C.;Huang,Y.L.;Chen,H.T.;Chen,Y.P.;Hsu,H.Y.
  3. Chem. Pharm. Bull. v.36 Three new neolignans, fargesones A, B and C, from he flower bubs of Magnolia fargesii Chen,C.C.;Huang,Y.L.;Chen,Y.P.;Hsu,H.Y.;Kuo,Y.H.
  4. Phytochemistry v.27 Terpenoids from leaves of Juniperus thurifera Feliciano,A.S.;Medarde,M.;Lopez,J.L.;Corral,J.M.M.;Puebla,P.;Barrero,A.F.
  5. Phytochemistry v.22 Sesquiterpene alcohols and triterpenoids from Liatris microcephala Herz,W.;Watanabe,K.
  6. Planta Med. v.56 (-)-Fargesol, A new lignan from the flower dubs of Magnolia fargesii Hwang,Y.L.;Chen,C.C.;Chen,Y.P.;Hsu,H.Y.;Kuo,Y.H.
  7. Bull. Chem. Soc. Jap. v.43 Structures of lignans of Magnolia fargesii Kakisawa,H.;Kusumi,T.;Hso,H.Y.;Chen,Y.P.
  8. Phytochemistry v.27 Components from Santolina rosmarinifolia, a subspecies rosmarinifolia and canescens Maqua,M.P.;Vines,A.C.G.;Caballero,E.;Grande,M.C.;Medarde,M.;Bellido,I.S.
  9. J. Chem. Soc. (C) Studies on sesquiterpenoids. Part XV. Structure and absolute configuration of oplodiol, a new sesquiterpene alcohol from Oplopanax japonicus(Nakai) Minato,H.;Ishikawa,M.
  10. Phytochemistry v.35 An insect growth inhibitory lignan from flower dubs of Magnolia fargesii Miyazawa,M.;Ishikawa,Y.;Kasahara,H.;Yamanaka,J.I.;Kameoka,H.
  11. Phytochemistry v.42 (_)-Magnofargesin and (+)-magnoliadiol, two lignans from Magnolia fargesii Miyazawa,M.;Kasahara,H.;Kameoka,H.
  12. Phytochemistry v.31 Phenolic lignans from flower buds of Magnolia fargesii Miyazawa,M.;Kasahara,H.;Kameoka,H.
  13. Coloured illustrations of Wakan-Yaku (The crude drugs in Japan, China and neighbouring countries) v.II Namba,T.
  14. Phytochemistry v.27 Isolation of α-corymbolol, an eudesmane sesquiterpene diol from Cyperus articulatus Nyasse,B.;Tih,R.G.;Sondengam,B.L.;Martin,M.T.;Bodo,B.
  15. Phytochemistry v.26 Lignans with platelet activating factor antagonist activity from Magnolia biondii Pan,J.X.;Hensens,O.D.;Zink,D.L.;Chang,M.N.;Hwang,S.B.
  16. Phytochemistry v.31 Sesquiterpenoids from the roots of Homalomena aromotica Sung,T.V.;Steffan,B.;Steglich,W.;Klebe,G.;Adam,G.
  17. Chinese Drugs of Plant Origin: Chemistry, Pharmacology, and Use in Traditional and Modern Medicine Tang,W.;Eisenbrand,G.