Lipase의 Transesterification반응에 의한 생물계면활성제의 합성

  • Sin, Yeong Min ;
  • Chung, Sook Hyun ;
  • Lee, Sang Ok ;
  • Shin, Hwa Kyoung ;
  • Lee, Tae Ho ;
  • 신영민 (부산대학교 미생물학과) ;
  • 정숙현 (동서대학교 식품공학과) ;
  • 이상옥 (부산대학교 미생물학과) ;
  • 신화경 (부산대학교 미생물학과) ;
  • 이희정 (부산대학교 미생물학과) ;
  • 이태호 (부산대학교 미생물학과)
  • Published : 1997.08.01

Abstract

Pseudomonas sp. lipase (lipase AK) catalyzed transesterification reaction between fructose and vinyl laurate in anhydrous pyridine. The product of this process was identified as monoester of fructose and vinyl laurate. The synthetic product has been found to be an excellent emulsifier. The synthetic bioemulsifier showed a good emulsification activity and stability in comparison with other commercial emulsifiers, and good emulsification activity on various emulsifying substrates.

Keywords

References

  1. Synthesis Enzyme catalysis in synthetic carbohydrate chemistry Drueckhammer, D. G.;W. J. Hennen;R. L. Pederson;C. F. Barbas;C. M. Gautheron;T. Krach;C. H. Wong
  2. Chem. Res. v.93 Transeserification Otera, J.
  3. J. Am. Chem. Soc. v.107 Resolution of racemic mixture via lipase catalysis in organic solvent Kirchner, G.;M. P. Scollar;A. M. Klibanov
  4. J. Am. Chem. Soc. v.108 Facile enzymatic preparation of monoacyled sugar in pyridine Therisod, M.;A. M. Klibanov
  5. J. Am. Chem. Soc. v.109 Regioselective acylation of secondary hydroxyl groups in sugars catalyzed by lipase in organic solvent Therisod, M.;A. M. Klibanov
  6. Tetrahedron v.42 Enzymes in organic synthesis Jones, J. B.
  7. Synthesis Esterolytic and lipolytic enzymes in organic synthesis Boland, W.;C. Frobl;M. Lorenz
  8. Chemtech v.16 Enzyme that work in organic solvent Klibanov, A. M.
  9. J. Org. Chem. v.46 Synthesis of an aspartame precursor by immobilized thermolysis in an organic solvent Oyama, K.;S. Nishimura;Y. Nonoka;T. Hoshimoto
  10. Trends Biotechnol. v.6 Enzymatic synthesis of oligosaccharides Nilson, K. G. I.
  11. Angew. Chem. Int. Ed. Engl. v.28 Enzymatic synthesis of selectively protected glycals Holla, E. W.
  12. J. Am. Chem. Soc. v.111 Chemoselective enzymatic monoacylation of bifunctional compouns Chinsky, N.;A. L. Margolin;A. M. Klibanov
  13. Tetrahedron Lett v.33 Enzyme-catalyzed synthesis of alkyl β-glucosidase in organic solvents Valerie L.;M. R. Willemot
  14. Biotechnol. Lett. v.14 Glucoside synthesis by glucoamylase or β-glucosidase in organic solvents Valerie L.;M. R. Willemot
  15. J. Chem. Soc. Perkin Trans. v.1 Stereochemical studies of enzymatic transglycosylation using Sulfolobus solfataricus Trincone A.;B. Nicolaus;L. Lama;A. Gambacorta
  16. Biotechnol. Lett. v.12 Alkyl-β-glucoside synthesis in water-organic two phase system Vulfson, E. N.;R. Patel;B. A. Law
  17. J. Chem. Soc., Chem. Commun. A highly selective enzyme-catalyzed esterification of simple glucosides Bjorkling F.;S. E. Godtfredsen;O. Kirk
  18. Biotechnol. Bioeng. v.39 Biological method for protection of 6-position of sucrose in synthesis of dicassharide high-intensity sweetner Jones J. D.;A. J. Hacking;P. S. J. Cheetham
  19. J. Am. Chem. Soc. v.115 Enzymatic synthesis of N- and O-linked glycopeptide Wong, C. H.;M. Schuster;P. Wang;P. Sears
  20. Biotechnol. Lett. v.15 Lipase-catalyzed monoacylation of fructose Schlotterbeck, A.;S. Lang;V. Wray;F. Wagner
  21. Biosci. Biochem. Bioeng. v.57 Preparation of N-monoalkyl land O-acyl derivative of allosamidine and their chitinase inhibitory activity Kinoshita, M.;S. Sakuda;Y. Yamada
  22. Tetrahedron Lett v.34 Total synthesis of the sulfated lipooligisaccharide signal involved in Rhizobium Meliloti-Alfalfa symbiosis Wang L. X.;C. Li;Q. W. Wang;Y. Z. Hui
  23. Agric. Biol. Chem. v.52 Formation of transfer products from soybean arabinogalactan and glycerol by galactanase from Penicillium citrinum Nakano, H.;S. Takenishi;Y. Watanabe
  24. Biotechnol. Lett v.18 Synthesis of biodegradable emulsifier using lipase in anhydrous pyridine Sin Y. M.;S. H. Chung;J. Y. Park;T. H. Lee