Preparation of Ferroelectric $BaTiO_3$ Thin Films on MgO-Buffered Si Substrates

MgO 완충층을 이용한 Si 기판상 강유전체 $BaTiO_3$ 박막의 제조

  • 김상섭 (순천대학교 금속공학고, 무기재료분야)
  • Published : 1997.04.01

Abstract

A study on the deposition and characterization of BaTiO3 thin films on MgO-buffered Si(100) substrates by sputtering was conducted. The MgO buffer layers were investigated as a function of deposition temperature. At lower substrate temperature, the MgO layers were not fully crystalline, but a crystallized MgO layer with (001) preferred orientation was obtained at the substrate temperature of $700^{\circ}C$. Partially (00ι) or (h00) textured BaTiO3 films were obtained on Si(100) with the MgO buffer layer grown at 700ι. While, randomly oriented BaTiO3 films with large-scale cracks on the surface were made without the MgO layer. The crystallographic orientation, morphology and electrical properties between the BaTiO3 films on Si with and without the MgO layer were compared using the BaTiO3 film on MgO(100) single crystal substrate as a reference system. Also the favorable role of the MgO layer as a buffer for growing of oriented BaTiO3 films on Si substrates was confirmed.

Keywords

References

  1. J. Vac. Sci. Technol. v.A12 no.4 Optical Thin Films for Wave Guide Applications J.M. Mir;J.A. Agostinelli
  2. J. Appl. Phys. v.76 no.2 Investigation of Barium Titanate Thin Films on MgO Substrates by Second-Harmonic Generation B. Bihari;J. Kumar;G.T. Stauf;P.C. Van Buskirk;C.S. Hwang
  3. Appl. Phys. Lett. v.65 no.12 Optical Clarity and Wave Guide Performance of Thin Films Perovskites on MgO F.J. Walker;R.A. Mckee;H.W. Yen;D.E. Zelmon
  4. J. Appl. Phys. v.78 no.9 Structural Characterzation of Epitaxial BaTiO₃Thin Films Grown by Sputter Deposition on MgO(100) S. Kim;S. Hishita;Y.M. Kang;S. Baik
  5. Jpn. J. Appl. Phys. v.33 no.9B Dielectric Property of Epitaxial Films of BaTiO₃Synthesized by Laser Ablation T. Nose;H.T. Kim;H. Uwe
  6. Appl. Phys. Lett. v.60 no.9 Epitaxial Growth of BaTiO₃Thin Films by Plasma-Enhanced Metalorganic Chemical Vapor Deposition C.S. Chem;J. Zhao;L. Luo;P. Lu;Y.Q. Li;P.Norris;B. Kear;F. Cosandey;C.J. Maggiore;B. Gallois;B.J. Wilkens
  7. J. Appl. Phys. v.69 no.2 Metalorganic Chemical Vapor Deposition of BaTiO₃Thin Films B.S. Kwak;K. Zhang;E.P. Boyd;A. Erbil;B.J. Wilkens
  8. J. Appl. Phys. v.74 no.3 Electrical Characteristics of Barium Titanate Films Prepared by Laser Ablation M.H. Yeh;Y.C. Liu;K.S. Liu;I.N. Lin;J.M.Y. Lee;H.F. Cheng
  9. Appl. Phys. Lett. v.52 no.25 Metalorganic Chemical Vapor Deposition of [100] textured MgO Thin Films B.S. Kwak;E.P. Boyd;K. Zhang;A. Erbil;B.J. Wikens
  10. J. Vac. Sci. Technol. v.A9 no.5 Growth and Microstructural Study of Radio Frequency Magnetron Sputtered MgO Films on Silicon R. Pinto;J.P. Poothra;S.C. Purandare;S.P. Pai;C.P. D'Souza;D. Kumar;M. Sharon
  11. J. Mat. Sci. Lett. v.10 Growth Structures of MgO Films on Si(100) and Si(111) Surfaces H.Z. Durusoy
  12. Appl. Phys. Lett. v.61 no.12 Temperature-Dependence of the Growth Orientation of Atomic Layer Growth MgO R. Huang;A.H. Kitai
  13. Jpn. J. Appl. Phys. v.34 no.4A Heteroepitaxial Growth of Yttria-Stabilized Zirconia Film on Silicon by Reactive Sputtering S. Horita;M. Murakawa;T. Fujiyama
  14. Appl. Phys. Lett. v.66 no.11 Heteroepitaxial Growth of BaTiO₃Films on Si by Pulsed Laser Deposition M.B. Lee;M. Kawasaki;M. Yoshimoto;H. Koinuma
  15. Appl. Phys. Lett. v.56 no.14 Epitaxial Growth of CeO₂Layers on Silicon T. Inoue;Y. Yamamoto;S. Koyama;S. Suzuki;Y. Ueda
  16. J. Appl. Phys. v.62 no.3 Epitaxial Gowth of NbN on an Ultrathin MgO/Semiconductor System M. Tonouchi;Y. Sakaguchi;T. Kobayashi
  17. Jpn. J. Appl. Phys. v.27 no.8 Y-Ba-Cu-O Thin Film on Si Substrate K. Harada;N. Fujimori;S. Yazu
  18. J. Am. Ceram. Soc. v.77 no.11 Chemical Etching of Silicon(100) by Hydrogen B.M. Gallois;T.M. Besmann;M.W. Stott
  19. S. Kim;S. Hishita
  20. Appl. Phys. Lett. v.58 no.20 Epitaxial MgO on Si(100) for Y-Ba-Cu-O Thin-Film Growth by Pulsed Laser Deposition D.K. Fork;F.A. Ponce;J.C. Tramontana;T.H. Gaballe
  21. J. Vac. Sci. Technol. v.16 no.2 Radio-Frequency-Sputtered Tetragonal Barium Titanate Films on Silicon J.K.G. Panitz;.C.C. Hu
  22. J. Appl. Phys. v.76 no.12 Epitaxial Growth and Dielectric Properties of BaTiO₃Films on Pt Electrodes by Reactive Evaporation Y. Yano;K. Iijima;Y. Daitoh;T. Terashima;Y. Bando;Y. Watanabe;H. Kasatani;H. Terauchi
  23. Appl. Phys. Lett. v.64 no.22 Electrical Properties and Poling of BaTiO₃Thin Films H.A. Lu;L.A. Wills;B.W. Wessels
  24. Mat. Res. Soc. Symp. Proc. v.243 Integrated Piezoelectric and Pyroelectric Devices from Thin Film Ferroelectrics M. Sayer;V. Kumar;D. Barrow;L. Zou;D. Amm