Phase Transition Study on Graphite at Room Temperature

고압하에서 방사광을 이용한 흑연에 대한 연구

  • Kim, Young-Ho (Department of Earth and Environmental Sciences and Basic Science Research Institute) ;
  • Na, Ki-Chang (Department of Earth and Environmental Sciences, Choongbuk National University)
  • Published : 1997.10.01

Abstract

High pressure X-ray diffraction study was carried out on a polycrystalline graphite to investigate the phase transition(s) at room temperature. Energy dispersive X-ray diffraction method was employed using a Mao-Bell type diamond anvil cell with an Wiggler synchrotron Radiation at the National Synchrotron Light Source. Sodium chloride power was used as the internal pressure sensor for the high pressure determinations as well as the pressure medium for quasihydrostatic pressure environment. Graphite transforms into a hexagonal didose not agree with the previously reported observations and this phase persists when pressure is released down to 0.1 MPa. This result dose not agree with the previously reported observations and this discrepancy would be due to the kinetics in phase transition as well as the uniaxially oriented pressure field in the diamond anvil cell.

Keywords

References

  1. Science v.140 Carbon-a new crystalline phase. Aust R.B.;Drickamer H.G.
  2. J. Applied Physics v.39 no.1 Pressure-Induced Phase Transformation in NaCI. Bassett W.A.;Takahashi T. Mao H.K.;Weaver J. S.
  3. J. Chem. Phys. v.46 Hexagonal diamond-a new form of carbon Bundy F.P.;Kasper J.S.
  4. Carbon v.34 no.2 The pressure-temperature phase and transformation diagram for carbon; Updated through 1994 Bundy F.P.;Bassett W.A.;Wehthers M.S.;Hemley R.J.;Mao H.K.;Goncharov A.F.
  5. Phys. Rev. v.B39 no.17 Graphite under pressure: Equation of state and first-order Raman modes. Hanfland M.;Beister H.;Syassen K.
  6. Phys. Rev. v.B30 no.10 Compression of the B2 high-pressure phase of NaCI. Heinz D.L.;Jeanloz R.
  7. Science v.159 X-ray diffraction: New high-speed technique based on X-ray spectroscopy Giessen B.C.;Gordon G.E.
  8. Jour. Petrol. Soc., Korea v.3 no.1 High pressure X-ray diffraction study on a graphite using Synchroton Radiation Kim Y.H.;Na K.C.
  9. J. Petrol. Soc., Korea v.5 no.2 Experimental study on the phase change of a graphite using piston cylinder, DAC and Synchrotron Radiation Na K.C.;Kim Y.H.
  10. Proc. Japan Academy v.67;B no.9 Formation of hexagonal diamond by room temperature compression of graphite. Utsumi W.;Yagi T.
  11. Phys. Rev. v.B46 no.10 High pressure in-situ x-ray diffraction study on the phase transformation from graphite to hexagonal diamond at room temperature. Yagi T.;Utsmi W.;Yamakata M.;Kikegawa T.;Shimomura O.
  12. Rev. Sci. Instrum. v.65 no.1 Graphite-diamond transition in gem anvil cells. Xu J.-A.;Huang E.
  13. Phys. Rev. v.B40 no.2 X-ray diffraction data for graphite to 20 GPa. Zhao Y.X.;Spain I.L.