Journal of the Korean Crystal Growth and Crystal Technology (한국결정성장학회지)

The Korea Association of Crystal Growth (한국결정성장학회)
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The structure and synthesis of intercalation compounds between layered basic copper acetate and alkyl sulfonates

알킬술폰이 삽입된 층상구조의 염기성 초산구리의 합성과 구조

  • Published : 1998.06.01
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Abstract

Layered basic copper acetate, $Cu(OH)(CH_3COO){cdot}H_2O$ was synthesized. Intercalation compounds of alkyl sulfonates into layered basic copper acetate have been synthesized via anionic exchange. From the X-ray diffraction data and the alkyl sulfonate size, the orientation of the intercalated alkyl sulfonate into layered basic copper acetate was determined.

층상구조를 가진 염기성 초산구리, $Cu(OH)(CH_3COO){cdot}H_2O$를 합성하였다. 또한 음이온 치환반응을 통해서 alkyl sulfonate를 염기성 초산구리에 삽입시켰다. X-선 회절 데이터와 alkyl sulfonate의 분자의 크기를 비교하여 층간 삽입된 초산구리의 공간배열을 확인하였다.

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References

  1. Chem. Rev. v.95 M. Ogawa;K. Kuroda
  2. J. Catal v.85 C. Busetto;G. Del Piero;G. Manara;F. Trifiro;A. Vaccari
  3. Science v.220 T. J. Pinnavaia
  4. J. Mater. Chem. v.5 S. Carlino;M.J. Hudson
  5. Chem. Mater. v.9 P. Gendraud;L. Bigey;C. Gueho;M.E. de Roy;J.P. Besse
  6. J. Chem. Soc. Chem. Commun K. Chibwe;W. Jones
  7. Solid State Ionics v.45 T. Sato;A. Okuwaki
  8. Intercalation Chemistry M.S. Whittingham;A.J. Jacobson
  9. Inorg. Chem. v.17 S.S. Cady;T.J. Pinnavaia
  10. Inorg. Chem v.34 V.R.L. Constantino;T.J. Pinnavaia
  11. J. Chem. Soc. Dalton Trans. J. Evans;M. Pillinger;J. Zhang
  12. J. Colloid Interface Sci. v.123 H. Kopka;K. Beneke;G. Lagaly
  13. J. Mater. Chem v.6 H. Tagaya;S. Ogata;H. Morioka
  14. J. Soild State Chem. v.131 N. Masciocchi;E. Corradi;A. Sironi;G.Moretti;G. Minelli;P. Porta
  15. 화학교육 v.21 최종인;이명진;김범모;오원석
  16. Handbook of Chemistry and Physics(70th ed) R. C. Weast