Preparation and Characterization of Water-Soluble Phosphate Glasses Containing Cu by Sol-Gel Method

졸-겔법에 의한 Cugkadb 인산염계 수용성 유리의 제조 및 특성

  • 오승환 (연세대학교 세라믹공학과) ;
  • 최세영 (연세대학교 세라믹공학과) ;
  • 김경남 (연세대학교 치과재료학교실)
  • Published : 1998.04.01

Abstract

Sol-gel derived phosphate water-sioluble glasses containing Cu were prepared. Powder-shape of glasses were added in D.I water used polyethylene bottle. After solution contained glass powder were submerged in water bath on 25$^{\circ}C$ their dissolution behavior/characteristics bactericidal effect and cytotoxicity test were evaluated. The maximum amount of Cu(35 mol%) via sol-gel method was more 5 mol% increased than that with melting process. The stage of total dissolution was more dominant than that of selective leaching dur-ing dissolution due to dissolved amount of glasses increased linearly with time. The ratio of Cu+ to {{{{ {Cu }^{2+ } }} was 3:7 so that the structure of glasses is more predominant 2-dimension chain structure than 3-dimenshion po-lymeric structue. The stage of total dissolution was more dominant than that of selective leaching during dissolution. Bactericidal effect against all bacteria showed that solutions which contained 40 ppm and 100 ppm of Cu killed 80 percentages of bacteria within 2 hours and 100 percentages of those within 12 hours. The results of cytotoxicity test for L929 cells showed no cytotoxicity were observed within 96 hours for dis-solved solution that contains 40 ppm and 100 ppm of Cu.

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