Manufacture of the Prealloyed Powder for Powder Metallurgy by the Ion-diffusion Process

이온확산법에 의한 분말야금용 합금강분의 제조

  • Yun, Seong-Ryeol (Kwangwoon University Department of Chemical Engineering) ;
  • Han, Seung-Hui (Kwangwoon University Department of Chemical Engineering) ;
  • Na, Jae-Hun (Kwangwoon University Department of Chemical Engineering) ;
  • Kim, Chang-Uk (Kwangwoon University Department of Chemical Engineering)
  • Published : 1998.02.01

Abstract

Cu, Ni, and Mo were ion-diffused into the pure steel powder in the aqueous solution of $(CuNO_3)_2$, $Ni(NO_3)_2)_2$, and $(NH_4)_6Mo_7O_{24}$, to form partial diffusion bond prealloyed steel powder. The mechanical properties, and compacting and sintering characteristics were investigated as a function of Cu. Ni and Mo contents. The results of the this research, it was found that the smallest change of size was observed, and the good degree of hardness and tensile strength was observed when 1.50wt%Cu, 1.75wt%Ni and 0.50wt%Mo was added each other. The powder metallurgy characteristics of partial diffusion bond prealloyed steel powder containing 1.50wt% of Cu, 1.75wt% of Ni and 0.5wt% of Mo were compared to those of distalloy $AB\textregistered$ which was manufactured in Hogani Corporation of Sweden. Partial diffusion bond prealloyed steel powder of this study had good degree of hardness and density, and its dimensional stability was same to that of pure steel powder. Under the same sintering density and temperature, the tensile strength of the ion powder from this research was $15~20Kg/\textrm{mm}^2$ larger than that of distalloy AB'. also the hardness was larger in the magnitude of Hv20-30. When the powder metallurgy heat-treated, hardness and tensile strength were substantially increased.

순첨분말에 $(CuNO_3)_2$, $Ni(NO_3)_2)_2$, $(NH_4)_6Mo_7O_{24}$를 이온확산시켜 부분확산합금강분으로 제조하고, Cu, Ni, Mo의 함량에 따른 성형성, 소결성, 기계적특성을 조사하였다. 연구결과 각각 Cu 1.50wt%, Ni 1.75wt%, Mo 0.50wt%일 때, 경도 및 인장강도는 우수하고, 수축률의 변화는 거의 없음을 알 수 있었다. 이러한 결과를 이용하여 Cu 1.50wt%, Ni 1.75wt%, Mo 0.50wt%가 함께 이온확산된 부분합금강분을 제조하여 특성을 조사하고, 스웨덴의 Hoganas사에서 수입되고 있는 부분합금강분(distalloy AB/ sub /)과 성형성, 소결성 및 기계적 특성을 비교하여 분석한 결과 본 연구방법에 의해 제조된 것이 성형성이 우수하고, 소결치수의 변화가 거의 없었으며, 같은 소결밀도 및 소경온도 조건에서 인장강도는 $15~20Kg/\textrm{mm}^2$, 경도는 Hv20-30 더 크고, 열처리 하였을 때도 경도 및 인장강도가 좀 더 양호한 결과를 얻었다.

Keywords

References

  1. Practice and application in powder metallurgy R.L.Sands
  2. Hand book of powder metallurgy chemical publication H.H.Hausner
  3. Iron powder NC100.24 report Hoganas corporation
  4. Powder metallurgy v.16 no.32 The effect of phosphorous additions on the tensile, fatigue, and impact strength of sintered steels based on the sponge iron powder and high-purity atomized iron powder P.Lindskog
  5. Powder metallurgy v.19 no.1 D.J.Hodkin;J.S.Pollock;W.Sutcliffe
  6. Mordern developements in powder metallurgy v.1 Recent trends of powder metallurgy production and research in Japan S.Kachi
  7. Mordern developements in powder metallurgy v.7 Effect of nickel addition copper alloys prepared by P/M N.C.Kothar
  8. Mordern developements in powder metallurgy v.8 Influence of copper and carbon levels on the heat-treatment and properties of high purity iron powder J.M.Copus;A.Maaref
  9. 메끼 분말을 이용한 Fe-Cu압분체의 소결현상 Shiro Kohara;Kiyohiko Tatsuzawa
  10. 분말야금학 문인형;윤덕용;이방식
  11. Mordern developements in powder metallurgy v.10 Use of additives to improve the machinability of sintered steels P.J.Anderson;J.S.Hirschhorn
  12. アトメル 技術資料 v.300M 編 新戶製鋼