DOI QR코드

DOI QR Code

Microstructure, Electrical Property and Nonstoichiometry of Light Enhanced Plating(LEP) Ferrite Film

  • Published : 1998.05.20

Abstract

A magnetic film was deposited on a slide glass substrate from aqueous solutions of $FeCl_2$ and $NaNO_2$ at 363 K. XRD analysis showed that the film was polycrystalline magnetite $(Fe_{3(1-{\sigma})}O_4)$ without impurity phase. The lattice constant was 0.8390 nm. Mossbauer spectrum of the film could be deconvoluted by the following parameters: isomer shifts for tetrahedral $(T_d)$ and octahedral $(O_h)$ sites are 0.28 and 0.68 mm/s, respectively, and corresponding magnetic hyperfine fields are 490 and 458 kOe, respectively. The estimated chemical formula of the film by the peak intensity of Mossbauer spectrum was $Fe_{2.95}O_4$. Low temperature transition of the magnetite (Verwey transition) was not detected in resistivity measurement of the film. Properties of the film were discussed with those of pressed pellet and single crystal of synthetic magnetites. On the surface of the film, magnetite particles of about 0.2 μm in diameter were identified by noncontact atomic force microscopy (NAFM) and magnetic force microscopy (MFM).

Keywords

References

  1. Jpn. J. Appl. Phys. v.22 Abe, M.;Tamaura, Y.
  2. IEEE Trans. Mag. Jpn. v.6 Itoh, T.;Hori, S.;Abe, M.;Tamaura, Y.
  3. J. Appl. Phys. v.57 Abe, M.;Tanno, Y.;Tamaura, Y.
  4. Thin Solid Films v.216 Abe, M.;Itoh, T.;Tamaura, Y.
  5. Trans. Mat. Res. Soc. Jpn. v.15B Abe, M.;Itoh, T.;Zhang, Q.
  6. J. Appl. Phys. v.75 Zhang, Q.;Itoh, T.;Abe, M.
  7. Chem. Mater. v.8 Palacin, S.;Hidber, P. C.;Bourgoin, J.;Miramond, S.;Fermon, C.;Whitesides, G. M.
  8. Phys. Rev. Lett. v.49 Binning, G.;Rohrer, H.;Gerberch, C.;Weibel, E.
  9. Science v.255 Wiesendanger, R.;Shvets, I. V.;Burgler, D.;Tarrach, G.;Guntherodt, H. J.;Coey, J. M. D.;Graser, S.
  10. Geophys. Res. Lett. v.23 Moloni, K.;Moskowitz, B. M.;Dahlberg, E. D.
  11. J. Solid State Chem. v.121 Yuan, C.;Yang, X.;Fu, D.;Lu, Z.;Liu, J.;Zhang, C.;Wu, T.;Wang, L.;Peng, S.
  12. Nature v.346 Tamaura, Y.;Tabata, M.
  13. Nefedova Dokl. Akad. Nauk SSR v.296 Alekseyeva, I. P.;Voronin, D. V.;Goldberg, I. S.
  14. Proc. Indian Acad. Sci. (Chem. Sci.) v.96 Honig, J. M.
  15. J. Alloy and Compounds v.229 Honig, J. M.
  16. Phys. Rev. B v.49 Kim, D.;Honig, J. H.
  17. Phys. Rev. B v.53 Kozlowski, A.;Metcalf, P.;Kakol, Z.;Honig, J. M.
  18. Phys. Rev. B v.54 Kozlowski, A.;Kakol, Z.;Kim, D.;Zalecki, R.;Honig, J. M.
  19. Z. Anorg. All. Chem. v.623 Kozlowski, A.;Kakol, Z.;Kim, D.;Zalecki, R.;Honig, J. M.
  20. J. Kor. Chem. Soc. v.41 Kim, D.;Cho, J. W.
  21. KOSEF report Kim, D.
  22. manuscript in preparation Park, J. C.;Kim, D.
  23. Mat. Lett. v.24 Chen, Q. W.;Qian, Y. T.;Chen, Z. Y.;Xie, Y.;Zhou, G. E.;Zhang, Y. H.
  24. J. Mag. Mag. Mat. v.140-144 Kleint, C. A.;Semmelhack, H. C.;Lorenz, M.;Krause, M. K.
  25. Hyperfine Interaction v.97;98 Voogt, F. C.;Fujii, T.;Hibma, T.;Hoefman, M.;Nisesen, L.
  26. J. Kor. Phy. Soc. v.28 Lee, J. S.;Itoh, T.;Abe, M.
  27. Bull. volc. Soc. Jpn. Ser. II v.5 Iwasaki, I.;Katsura, T.;Ozawa, T.;Yoshida, M.;Mashima, M.;Haramura, H.;Iwasaki, B.
  28. Solid State Comm. v.6 Haley, G.;Mullen, J. G.;Honig, J. M.
  29. J. Solid State Chem. v.120 Kodama, T.;Tabata, M.;Sano, T.;Tsuji, M.;Tamaura, Y.
  30. Surface Sci. v.331-333 Voogt, F. C.;Hibma, T.;Zhang, G. L.;Hoefman, M.;Niesen, L.
  31. J. Appl. Phys. v.75 Proksch, R.;Foss, S.;Orme, C.;Sahu, S.;Moskowitz, B.
  32. Ber. Bunsenges. Phys. Chem. v.86 Dieckman, R.
  33. Ber. Bunsenges. Phys. Chem. v.811 Dieckman, R.;Schmalzried, H.
  34. J. Rev . Sci. Instrum. v.55 Shepherd, J. P.;Sandberg, C.
  35. Mat. Res. Bull. v.13 Harrison, H. R.;Aragon, R.
  36. JCPDS (Joint Committee on Powder Diffraction Standards) data base 19-629 JCPDS
  37. The Iron Oxides Cornell, R. M.;Schwertmann, U.
  38. The Powder Method Azaroff, L. B.
  39. J. Mag. Mag. Mat. v.140-144 Klent, C. A.;Semmelhack, H. C.;Lorenz, M.;Krause, M. K.
  40. Phys. Rev. B v.46 Wang, P.;Kakol, Z.;Wittenauer, M.;Honig, J. M.