The Preparation of K-GIC and its Anodic Characteristics of Lithium Ion Secondary Battery

K-GIC의 합성 및 리튬이온이차전지에서의 부극특성

K-GIC of the new carbon electrode to improve performance of carbon negative electrode in lithium ion secondary battery was prepated and its electrical characteristics were studied. Form this study, intercalated K quantity was increased in order of $2>3>1mole/{\ell}$ of KCl solution. And, for KCl solution of 1mole, the mole ratio of carbon and potassium was 156~388 carbon/potassium. The proper condition of K-GIC preparation was KCl solution of $1mole/{\ell}$, reaction temperature of $700^{\circ}C$, reaction time of 1 hour. From this condition, the intercalation and deintercalation behavior of lithium was very excellent. Also the reversibility was excellent.

리튬이온이차전지에 사용되는 탄소부극의 성능을 향상시키기 위하여 새로운 탄소부극으로서 K-GIC를 합성하여 전기화학적 특성을 조사하였다. K의 삽입량은 KCl 수용액의 농도가 $2>3>1mole/{\ell}$의 순으로 증가하였으며 $1mole/{\ell}$의 KCl 수용액으로 처리하였을 때 K와 C의 mole 비는 156~388 carbon/potassium이었다. K-GIC의 합성조건을 $1mole/{\ell}$ KCl 수용액으로 $700^{\circ}C$에서 1시간으로 처리하였을 때 가장 우수한 리튬의 삽입과 탈삽입 거동을 나타냈으며 가역성 또한 우수하였다.