Abstract
We synthesized the nonlinear optical (NLO) PI-SOT(polyimide system, 4-[N,N-bis(hydroxyethyl)amino-4,-($\beta$-cyano-$\beta$-methylsulfonyl)vinyl]azobenzene) polymer with high electro-optic coefficients as well as good thermal and temporal stabilities of the elector-optic coefficient ${\gamma}_33$ by the simple Mitsunobu reaction. By using the simple reflection method of C. C. Teng, we measured the thermal and temporal stabilities of the electro-optic coefficient ${\gamma}_33$ of corona-poled PI-SOT polymer at the wavelength of 632.8 nm and 852 nm, respectively. At the temperature of $20^{\circ}C$, the electro-optic coefficient ${\gamma}_33$ of corona-poled PI-SOT polymer were 25.12 pm/V at the wavelength of 632.8 nm and 5.40 pm/V at the wavelength of 852 nm. These values were highly stabilized for more than 60 days at 2$0^{\circ}C$ and stabilized within 6% for more than 10 hours at $100^{\circ}C$.
Mitsunobu 반응을 이용하여 전기광학계수 $\gamma_{33}$크고 열적 .시간적으로 안정적인 폴리이미드(polyimide)계고분자 용액인 PI-SOT(폴리이미드계 4-[N,N-bis(hydroxyethyl)amino4'($\beta$cyano-$\beta$methylsulfonyl)vinyl]azobenzene)고분자를 합성하였다. C.C. Teng의 단순반사법을 이용하여 코로나 폴링으로 극성 배향시킨 PI-SOT 박막의 전기광학계수 $\gamma_{33}$의 열안정성 및 시간안정성을 파장 632.8 nm와 852nm에서 측정하였다. 그 결과 상온에서 전기광학계수$\gamma_{33}$은 파장 632.8nm서 25.12 pm/V이고, 852 nmsns 5.40pm/V였다. 이 값들은 상온에서 60일 이상 장기간 안정적으로 유지되었으며, $100^{\circ}C$의 고온에서도 10시간내에서 6% 이내로 안정된 값을 유지하였다.
