$\beta$-SiC Formation Mechanisms in Si Melt-C-SiC System

용융 Si-C-SiC계에서 $\beta$-SiC 생성기구

  • 서기식 (한국과학기술연구원 재료연구부) ;
  • 박상환 (한국과학기술연구원 재료연구부) ;
  • 송휴섭 (한국과학기술연구원 재료연구부)
  • Published : 1999.06.01

Abstract

${\beta}$-SiC formation mechanism in Si melt-C-SiC system with varying in size of carbon source was investigated. A continuous reaction sintering process using Si melt infiltration method was adopted to control the reaction sintering time effectively. It was found that ${\beta}$-SiC formation mechanism in Si melt-C-SiC system was directly affected by the size of carbon source. In the Si melt-C-SiC system with large carbon source ${\beta}$-SiC formation mechanism could be divided into two stages depending on the reaction sintering time: in early stage of reaction sintering carbon dissolution in Si melt and precipitation of ${\beta}$-SiC was occurred preferentially and then SIC nucleation and growth was controlled by diffusion of carbon throughy the ${\beta}$-SiC layer formed on graphite particle. Furthmore a dissolution rate of graphite particles in Si melt could be accelerated by the infiltration of Si melt through basal plane of graphite crystalline.

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References

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