Fabrication and Electrical Characteristics of SrZr$_{0.95}$M$_{0.05}$O$_3$-$\delta$ and BaZr$_{0.95}$O$_3$-$\delta$(M=Ga, Y)

SrZr$_{0.95}$M$_{0.05}$O$_3$-$\delta$ 및 BaZr$_{0.95}$O$_3$-$\delta$(M=Ga, Y) 의 제조와 전기적 특성

  • 편영미 (서울시립대학교 재료공학과) ;
  • 유광수 (서울시립대학교 재료공학과)
  • Published : 1999.07.01

Abstract

Specimens of SrZr0.95Ga0.05O3-$\delta$, SrZr0.95Y0.05O3-$\delta$, BaZr0.95Ga0.05O3-$\delta$ and BaZr0.95Y0.05O3-$\delta$ were fabricated by a solid-state reaction method and subsequent sintering at 150$0^{\circ}C$ to 1$600^{\circ}C$ The microstructures and electrical characteristics of the specimens were studied. Only BaZr0.95Ga0.05O3-$\delta$ showed dense microstructure and had typical impedance spectra at various temperature. Its electrical conductivity by impedance analysis was 2.7$\times$10-3$\Omega$-1.cm-1 at 90$0^{\circ}C$ in air. The BaZr0.95Ga0.05O3-$\delta$ exhibited lower grain rsistance in wet atmosphere than in dry atmosphere and the reduction of resistance is due to the proton conduction.

Keywords

References

  1. Solid State Ionics v.3/4 Proton Conduction in sintered Oxides and its Application to Steam Electrolysis for Hydrogen Production H. Iwahara;T. Esaka;H. Uchida;N. Maeda
  2. Solid State Ionics v.77 Technological Challenges in the Application of Proton Conducting Ceramics H. Iwahara
  3. Solid state Ionics v.86 Ptoton Conducting Ceramics and Their Applications H. Iwahara
  4. Solid State Ionics v.86-88 Reduction of Nitrogen Oxide by a Steam Electrolysis Cell Using a Proton Conducting Electrolyte T. Kobayashi;S. Morishita;K. Abe;H. Iwahara
  5. Solid State Ionics v.97 no.1-15 On the Development of Proton Conducting Materials for Technological Applications K.D. Kreuer
  6. Solid State Ionics v.79 Perovskite Solid Electrolytes : Structure Transport Properties and Fuel Cell Applications N. Bonanos;K. S. Knight;B. Ellis
  7. Solid State Ionics v.61 Protonic Conduction in Calcium, Strontium and Barium Zirconates H. Iwahara;T. Yajima;T. Hibino;K. Ozaki;H. Suzuki
  8. Solid State Ionics v.47 Proton Conduction in the Single Crystals of Y-doped SrZrO₃ H.H. huang;M. Ishigami
  9. Solid State Ionics v.51 Protonic Conduction in SrZrO₃-based Oxides T. Yajima;H. Suzuki;T. Yogo;H. Iwahara
  10. Solid State Ionics v.61 Defect Structure of SrZrO₃ J.A. Larincha;J.T. Frade;F.M.B. Margues
  11. Solid State Ionics v.77 Persistent Spectral Hole-Burning of $Eu^{3+}$ and $Pr^{3+}$ in $SrZr_{1-x}Y_xO_3$ Crystals H. Yugami;S. Matsuo;M. Ishigame
  12. Solid State Ionics v.77 Thin Films of Proton Conducting SrZrO₃-Ceramics Prepared by the Sol-Gel Method J. Eschenbaum;J. Rosenberger;R. Hempelmann;D. Nagengast;A. Weidinger
  13. Solid State Ionics v.100 Electrical and Mechanical Properties of Proton Conducting $SrCe_0.95Yb_0.05O_{3-\alpha}$ K.J. de Vries
  14. Operating Manual(version 1.4) Impedance/Gain Phase Graphing and Analysis Software ZView for Windows
  15. Impedance Spectroscopy J.R. Macdonald
  16. Solid State Ionics v.77 Comparison of Calcium-Doped Barium Cerate Solid Electrolytes Prepared by Different Routes S.D. Flint;R.C.T. Slade