Behaviors of Abnormal Expansion in $Ba_2Ti_9O_{20}$ Ceramics during Calcination Process

$Ba_2Ti_9O_{20}$ 요업체의 하소공정중 이상팽창 거동

  • Published : 1999.12.01

Abstract

Behaviors of abnormal expansion during calcination process of Ba2Ti9O20 ceramics and its related effects on the sintering characteristics were investigated as a function of precursors. When BaCO3 and TiO2 powders were used as starting materials. BaTi4O9 phase which has relatively large molar volume was formed drastically with abnormal ex-pansion during the calcination at 95$0^{\circ}C$ to 115$0^{\circ}C$ ON the contrary using BaTiO3 and TiO2 powders as starting materials led to retardation of the formation of BaTi4O9 phase and concurrently suppressed the abnormal expansion during cal-cination process. Especially the calcined powder of BaTiO3 and TiO2 had advantages in the densification and formation of Ba2Ti9O20 single phase in the sintering process.

Keywords

References

  1. 소결 . 치밀화, 입성장과 미세조직 강석중
  2. J. Am. Ceram. Soc. v.77 no.9 Effect of Calcination on the Sintering of Gel-Derived Zirconia-Toughened Alumina P. D Exter;L. Winnubst;T. H. P. Leuwerink;A. J. Burggraaf
  3. J. Am. Ceram. Soc. v.67 no.9 Influence of Aggregates on Sintering F. W. Dynys;J. W. Halloran
  4. J. Am. Ceram. Soc. v.64 no.1 Agglomerate and Particle Size Effects on Sintering Yittria-Stabilized Zirconia W. H. Rhodes
  5. J. Am. Ceram. Soc. v.78 no.12 Reaction Sintering of ZnO-$Al_2O_3$ W. S. Hong;L. C. D. Jonghe
  6. 세라믹 유전체 공학 이경희
  7. 요업학회지 v.24 no.1 Barium Titanate를 고상반응으로 합성할 때 수반하는 팽창과 상과의 관계 이응상;임대영
  8. 요업학회지 v.22 no.6 Barium Titanate를 고상반응으로 합성할 때 일어나는 이상팽창에 관한 연구 이응상;임대영
  9. 요업학회지 v.23 no.4 Barium Titanate를 고상반응으로 합성할 때 팽창에 영향을 주는 분위기소성에 관한 연구 이응상;임대영
  10. 요업학회지 v.24 no.5 $BaCO_3-TiO_2$계의 고상반응에 관한 연구 이응상;황성연;임대영
  11. 요업학회지 v.26 no.6 $BaTiO_3$이론조성과$BaCO_3$가 과잉인계에서 팽창과 상에 관한 연구 김종옥;이풍헌;임대영
  12. Ceramiurgia Int. v.6 no.2 Expansion During the Reaction Sintering of PZT Y. Nakamura;S. Chandratreya;R. M. Fulrath
  13. Proc. of UNITECR'95 Congress v.1 Effect of Corundum/Perclase Sizes on Expansion Behavior During Synthesis of Spinel Z. Nakagawa;N. Enomoto; I. S, Yj;K. Asano
  14. J. Am. Ceram. Soc. v.74 no.8 Phase Relation in the Barium Titanium Oxide System K. W. Kerby;B. A. Wechsler
  15. Quantative Stereology E. E. Underwood
  16. J Am. Ceram. Soc. v.52 no.8 Average Gram Size-in Polycrystalline Ceramics M. I. Mendelson
  17. J. Am. Ceram. Soc. v.58 no.9-10 $Ba_2Ti_9O_20$as Microwave Dielectric Resonator J. K. Plourde;D. E. Linn;H. M O'Bryan;J. Thomson
  18. J. Am. Ceram. Soc. v.68 no.2 Temperature Dependent Phase Boundaries for$BaTi_4O_9,\;Ba_4Ti_13O_30\;and\;Ba_6Ti_17O_40$ H. M. O'Bryan, Jr;J. Thomson
  19. Am. Ceram. Soc. Bull. v.72 $BaTi_4O_9/Ba_2Ti_9O_20$-Based Ceramics Resurrected for Microwave Modern Applications T. Negas;G. Yenge;S. Bell;N. Coats;I. Minis
  20. J. Am. Ceram. Soc. v.57 no.10 A New$BaO-TiO_2$Compound with Temperature-Stable High Permittivity and Low Micrpwave Loss H. M. O'Bryan. Jt.;J. K. Plourde;J. Thomson. Jr;D. F. Linn
  21. J. Am. Ceram. Soc. v.58 no.9-10 $Ba_2Ti_9O_20$as a Mircrowave Dielectric Resonatoi J. K. Plourde;D. F. Linn;H. M. O. Bryan, Jr;J. Thomson, Jr.
  22. J. Am. Ceram. Soc. v.78 no.5 Microwave Characteristics of BaO-TiO₂Ceramics Prepared via a Citrate Route J. H. Choy;Y. S. Han;S. H. Hwang;J. H. Choi;M. Itoh
  23. J. Am. Ceram. Soc. v.66 no.1 $Ba_2Ti_9O_20$Phase Equilibria H. M. O'Bryan;J Thomson
  24. J. Am. Ceram. Soc. v.71 no.10 Factors Affecting the Formation of$Ba_2Ti_9O_20$ J. M. Wu;H. W. Wang
  25. J. Am. Ceram. Soc. v.74 no.5 Sol-Gel Process for the Preparation of$Ba_2Ti_9O_20$and$BaTi_5O_11$ H. C. Lu;L. E. Burkhart;G. L. Schrader
  26. J. Mater. Res. v.11 no.8 Effect of$BaSnO_3$on the Microwave Dielectric Properties of$Ba_2Ti_9O_20$ K. H. Yoon;J. B. Kim;W. S. Kim;E. S. Kim
  27. J. Am. Ceram. Soc. v.82 no.2 Dielectric Properties of Microstructure-Controlled$Ba_2Ti_9O_20$Resonator W. Y. Lin;R. F. Speyer
  28. J. Am. Ceram. Soc. v.82 no.5 Microwave Properties of$Ba_2Ti_9O_20$doped with Zirconium and Tin Oxides W. Y. Lin;R. F. Speyer;W. S. Hackenberger;T. R. Shroul
  29. 요업학회지 v.30 no.12 공침법에 의한$Ba_2Ti_9O_20$합성과$ZrO_2$첨가효과에 관한 연구 이병하;이경희;이헌식;전성용
  30. J. Mater. Res. v.14 no.5 Fabrication of Undoped Near-Monophase$Ba_2Ti_9O_20$via Rapid Thernal Processing W. Y.Lin;R. F. Speyet
  31. J. Am. Ceram. Soc. v.57 no.12 Phase Equilibria in the$TiO_2$-Rich Region of the System BaO-$TiO_2$ H. M. O'Bryan. Jr;J. Thomson Jr.
  32. The Merck Index-11th Edition S. Budavari;M. J. O'Neil;A. Smith;E. Heckelman
  33. X-ray Diffraction Procedures H. P. Plug;L. E. Alexander
  34. X선 회절의 기초 한봉희
  35. J. Am. Ceram. Soc. v.71 no.1 $BaO-TiO_2-WO_3$Microwave Ceramics and Crystallinne$BaWO_4$ S. Nishigaki;S. Yano;H. Kato;T. Hiral;T. Nonomura