Microstructure and Mechanical Strength of Hardened Paste of Hydroxyapatite Cement Containing Whisker Phase

휘스커상을 함유한 수산화아파타이트시멘트 경화체의 미구조-강도 특성

  • 손영도 (경남대학교 신소재공학부) ;
  • 송태웅 (경남대학교 신소재공학부)
  • Published : 1999.12.01

Abstract

In order to improve the density and the mechanical strength without change in chemical composition the hardened pastes of hydroxyapatite cement were reinforced with powders and/or whiskers of hydroxyapatite. The powders behaved as a seed of hydroxyapatite formation rather than a filler while the whiskers were mrerly dispersed in matrix and capillary pores of the hardened bodies leading to increase in mechanical strength. But the increase in strength But the increase in strength was nnt enough owing to the lack of homogeneous dispersion of the fibers. The highest diametral tensile strength of 18.5 MPa was measured at the hardened hydroxyapatite body in which well-dispersed whisker phase formed uniformly during hydro-thermal curing of power-added and dry-formed hydroxyapatite cement.

Keywords

References

  1. World Scientific. An Introduction to Bioceramics L. L. Hench;J. Wilson;L. L. Hench(ed)
  2. Hydroxyapatite and Related Materials Calcium Phosphate Apatites in Nature D. K. Smith.;P. W. Brown.(ed)
  3. Hydroxyapatite and Related Materials Biological and Synthetic Apatites R Z. LeGeros;P.W. Brown(ed)
  4. Hydroxyapatite and Related Materials Thermal Stability fo Synthetic Hydroxyapatite Y. Fang;D. K. Agrawal;D. W. Roy;P. W. Brown.(ed)
  5. J. Mater. Sci. : Materials in Medicine v.6 Properties and Mechanisms of Fast-Setting Calcium Phosphate Cements K. Ishikawa;S. Takagi;L. C. Chow;Y. Ishikawa
  6. J. Mater. Sci. : Materials in Medicine v.6 Calcium Phosphate Cement: Invitro and Invivo Studies of the α-Tricalcium Phopshate-Dicalcium Phosphate Dibasic Tetrcalcium Phosphate Monoxide System K. Kurashina;H. Kurita;M. Hirano;J. M. A. de Blieek;C. P. A. T. Klein;K. de Groot
  7. J. Mater. Sci. : Materials in Medicine v.4 Compressive Strength and Diametral Strength Tensle Strength of Some Calcium Orthophosphate Cements: a Pilot Study O Bermudez;M. G. Boltong; F C M. Driessens;J. A. Planell
  8. Hydroxyapatite and Related Materials Formation fo Hydroxyapatite in Cement System C. Chow;S. Takagi;K. Ishikawa;P. W. Brown.(ed)
  9. Kor. J. Ceram. v.3 no.2 Synthesis and Properties of Self-hardeneing Calcium Phosphate Cements for Bilogical Application T. W. Song;H. Y. Kim
  10. J. Dem. Res. v.69 no.12 Setting Reactions and Compressive Strength of Calcium Phosphate Cements Y Fukase;E. D. Eanes;S. Tagagi;L. C. Chow;W. E. Brown
  11. Mater Res. Symp. Proc. v.179 Self-setting Calcium Phosphate Cements L. C. Chow;S. Tagagi;P. D. Costantino;C. D. Friedman
  12. J. Am. Ceram. Soc. v.74 no.8 Development of Self-setting Calcium Phosphate Cements L. C. Chow
  13. J. Am. Ceram. Soc. v.74 no.5 Kinetics of Hydroxyapatite Formation at Low Temperature P. W. Brown;M. T. Fulmer
  14. J. Am. Ceram. Soc. v.74 no.8 Variation in Solution Chemistry During the Low-Temperature Foramation of Hydroxyapatite P. W. Brown;N. Hocker;S. Hoyle
  15. J. Am. Ceram. Soc. v.74 no.1 Phase Relationship in the Ternary System$CaO-P_2O_5-H_2O$at$25^{\circ}C$ P. W. Brown
  16. Nippon-Kagaku- Kaish v.10 Hydrothermal Synthesis of Needle-like Apatite Crystals M Yoshimura;H. Suda;K. Okamoto;K. Ioku
  17. Bioceramics;Proceedings of the 5th Int. Symp. Ceram. Medicine v.5 Preparation and Characterization of Hydroxyapatite Whiskers by Hydrothermal Method H Suda;N. Asaoka;M. Yoshimura;T. Yamamuro;T. Kokubo;T Nakamura
  18. Hydroxyapatite and Related Materials Hydrothermal Processing of Hydroxyapatite: Past, Present, and Future M. Yoshimura;H. Suda;P. W. Brown(ed);B. Constantz.(ed)