왁스(wax) 함침형 나일론 6의 합성과 그의 기계적 성질에 관한 연구

A Study on Synthesis and Mechanical Properties of Wax-Impregnated Nylon 6

  • 발행 : 1999.09.01

초록

In order to make an advanced dry-friction engineering material, wax-impregnated nylons were synthesized by anionic polymerization of $\varepsilon$-caprolactam in the presence of apraffin wax. DNX-125S, which has lowest melting point among four different kinds of waxs investigated, showed excellent miscibiility with $\varepsilon$-carprolactam and no effect on the polymerization reaction. Five different kinds of wax-impregnated nylons from of DNW-125S content 0% to 8% were synthesized and tested. Among the samples, wax-free nylon has the highest yield and tensile strength and hardness, while the specimen with2% wax has the largest elongationi and energy absorption to break. The wax-impregnated nylon with a wax content 6% showdd the smallest friction coefficient under slow sliding speed and low load. Bus as the sliding speeds were increased to high, thespcieimen with 8% wax has better friction property.

키워드

참고문헌

  1. 기계재료 강석춘(역);K. G. Budinski(저)
  2. J. Polym. Sci. v.48 Champetire, G.;Sekiguchi, H.
  3. Comprehensive Polymer Science v.3 Sebenda, J.;Tipper, C. F. H.(ed.);Bamford, C. H. (ed.)
  4. Macromol.Chem. v.193 no.10 Stehlicek, J.;Puffr, R.
  5. Polym. J. v.28 no.5 Ueda, K.;Yamada, K.;Nakai, M.;Matsuda, T.;Hosoda, M.;Tai, K.
  6. 대한기계학회논문집 A권 v.22 no.11 강석춘;정대원
  7. Friction and Lubrication of solid Bowden, F. P.;Tabor, P.
  8. Trobology의 개론 이봉구(역)
  9. Friction, An Introduction to Tribology Bowden, F. P.;Tabor, P.