A Study on the Phosphorescent Characteristics of Blue $\textrm{Ca}\textrm({Al}_{0.97}\textrm{B}_{0.03})_2\textrm{O}_4$: $\textrm{Eu}^{+2},\;\textrm{Nd}^{+3}$ Phosphor

청색 $\textrm{Ca}\textrm({Al}_{0.97}\textrm{B}_{0.03})_2\textrm{O}_4$: $\textrm{Eu}^{+2},\;\textrm{Nd}^{+3}$ 형광체의 잔광 특성에 관한 연구

  • Kim, Dae-Su (Dept. of MaterialsScience & Engineering Donkook University) ;
  • Lee, Im-Ryeol (Dept. of MaterialsScience & Engineering Donkook University)
  • 김대수 (단국대학교 재료공학과) ;
  • 이임렬 (단국대학교 재료공학과)
  • Published : 1999.01.01

Abstract

The change of phosphorescent property with chemical modification and co-doping of Nd as an auxiliary activator in CaAl$_2$$O_4$: Eu\ulcorner, Nd\ulcorner phosphor, employing Nd\ulcornerion(0.6%) and an co-activator maintained its afterglow for 4.5 hours. And also the initial persistent brightness and phosphorescent property were further improved both by substituting Al by B atoms and incorporation of Nd\ulcorner ion. It was found that the persistent time was 30 hours for&Ca(Al_{0.97}\;B_{0.03}) $_2$$O_4$:EU\ulcorner(0.3%), Nd\ulcorner(0.6%) phosphor.

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References

  1. Proceeding of the 4th International Display Workshops Y.Murazaki;K.Arai;K.Ichsnomiya;H.Tamaki;T.Oish
  2. U.S. patent 5,424,006 Y.Murayama;N.Takeuchi;Y.Aoki;T.Matsurzawa
  3. J. Electrochem. Soc. v.144 no.9 T.Katsumata;T.Nabae;K.Sasajima;S.Komuro;T.Morikawa
  4. Proceeding of the 4th International Display Workshops T.Matsuzawa
  5. J. Luminesecence v.72-74 H.Yamamoto;T.Matsuzawa
  6. J. Electrochem. Soc. v.143 no.8 T.Matsuzawa;Y.Aoki;N.Takeuchi;Y.Murayama
  7. J. Mater. Chem. v.7 no.8 B.M.Mohamed;J.H.Sharp
  8. J. Electrochem. Soc. v.115 no.6 F.C.Palolla;A.K.Levine;M.R.Tomcus
  9. U.S. patent 5,376,303 M.R.Royce;H.Tamaki;Y.Murazaki
  10. J. Electrochem. Soc. v.112 R.C.Ropp