Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
권호 표지

Characteristics of Crosslinked Resin Modified with Nitriles

니트릴에 의해 개질된 가교구조 수지의 특성

  • 심미자 (서울시립대학교 생명과학과)
  • Published : 1999.04.01
Download PDF
⟨ Previous Next ⟩

Abstract

The cure mechanicsm and cure kinetics of diglycidyl ether of bisphenol A(DGEBA)/4,4'-methylene dianiline(MDA)/nitrile(MN, SN, GN) systems were studied by FT-IR and DSC to develop new applications in the biomedical polymer fields. The network structure of the DGEBA/MDA system was changed to the chain-extended network structure by the addition of nitriles. The reactions contributed to the chain extension were the primary amine-nitrile and hydroxyl-nitrile reactions. The chain-extended network structure could be indirectly proved by the decrement of T\ulcorner and the increment of impact strength with the increasing nitrile content. The cure rate of DGEBA/MDA/nitrile system was lower than that of DGEBA/MDA system due to the disturbance of nitrile group in the reaction of primary amine and epoxide groups.

Keywords

References

  1. Bolld Compatible Materials and Devices : Perspective Toward the 21st Centry C.P. Sharma;M. Szycher(ed.)
  2. Encyclopedia of Me. Dev. Instr. J.G. Webster(ed.)
  3. Biocompatible Polymers, Metals and Composites M. Szycher(ed.)
  4. J. Appl. Polym. Sci. v.29 no.2481 C.C. Riccardi;H.E.Adabbo;R.J.J. Williams
  5. J. Appl. Polym. Sci. v.29 no.3713 R.E.Smith;F.N. Larsen;C.L. Long
  6. J. Appl. Polym. Sci. v.31 no.1309 D.J. Belton;E.Sullivan
  7. Polym. Eng. and Sci. v.27 no.788 C.S. Chern;G.W. Poehlein
  8. J. Appl. Polym. Sci. v.32 no.3445 C.C. Riccardi;R.J.J. WIlliams
  9. Thermal Characterization of Polymeric Materials E.A. Tur(ed.)
  10. J. Appl. Polym. Sci. v.33 no.999 R.J.Morgan;E.T.Mones
  11. J. Appl. Polym. Sci. v.19 no.1539 J.C. Paterson-Jones
  12. J. Polym. Sci. v.15 no.2393 K. Dusek;M. Bleha
  13. Mater. Chem. Phys. v.44 no.74 M.J. Shim(et.al.)
  14. Mater. Chem. Phys. v.50 no.256 M.J. Shim(et. al.)
  15. Polym. J. v.30 no.73 M.J. Shim(et.al.)
  16. Thermochimica Acta v.323 no.37 M.J. Shim(et.al.)