Preparation of Silicon Oxide Thin Film using Hydrofluorosilicic Acid

규불화수소산을 이용한 실리콘 산화물 필름 제조에 관한 연구

  • 박은희 (충남대학교 공과대학 공업화학과) ;
  • 정흥호 (충남대학교 공과대학 공업화학과) ;
  • 임헌성 (한국화학연구소 분석부) ;
  • 홍성수 (호서대학교 공과대학 화학공학부) ;
  • 노재성 (충남대학교 공과대학 공업화학과)
  • Published : 1999.04.01

Abstract

Typical metal oxide thin films having optical and electrical properties are widely used as inorganic functional materials. Liquid phase deposition(LPD) method, a new low temperature process, has been developed for the several advantages of no vacuum system, low cost, high throughput, and low processing temperature(<$50^{\circ}C$). Silica powder was added to 40wt% hydrofluoro-silicic acid($H_2$SiF\ulcorner) to obtain an immersing solution of silica-saturated hydrofluorosilicic acid solution. Boric acid solution was continuously added in the range from 0 to 0.05M to prepare supersaturated hydrofluorosilicic acid solution. LPD $SiL_2$film was formed with the variation of added amount of $H_2$O. The SiO$_2$thin film could be prepared from hydrofluorosilicic acid by LPD method. The thickness of LPD $_SiO2$film was influenced by the boric acid concentration and added amount of $H_2$O. Silicon in thin film existed as SiF\ulcorner by Raman spectrum.

Keywords

References

  1. J. Electrochem. Soc. : Solid-State Science and Technology v.135 no.8 H. Nagayama;H. Honda;H. Kawahara
  2. Appl. Phys. Lett. v.64 no.15 Jenq-Shiuh Chou;Si-Chen Lee
  3. J. Electrochem. Soc. v.140 no.8 T. Homma;T. Katoh;Y. Yammada;Y. Murao
  4. J. Electrochem. Soc. v.141 no.11 Jenq-Shiuh Chou; Si-Chen Lee
  5. NEW GLASS v.7 no.4 Juichi Ino
  6. J. Electrochem. Soc. v.141 no.11 Ching-Fa Yeh;Chun-Lin Chen; Guan-Hong Lin
  7. 1995 International Conference on Solid State Devices and Materials v.596 Tso-Hung Fan;Shyue-Shyh Lin;Ching-Fa Yah
  8. IEEE Transactions on electron devices v.41 no.2 Ching-Fa Yeh;Shyue-Shyj Lin;Tzung-Zu Yang;Chun-Lin Chen;Yu-Chi Yang
  9. J. Electrochem. Soc. v.142 no.10 Ching-Fa yeh;Chun-Lin Chen
  10. J. Non-Crystalline Solids v.151 no.102 Koichi Awazu;Hiroshi Kawazoe;Kazuhiko Seki