Bulletin of the Korean Chemical Society

  • 제20권4호
  • /
  • Pages.436-440
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  • 1999
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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High Resolution Optical Spectroscopy of mer-[Cr(dpt)(Gly-Gly)]ClO₄

  • 발행 : 1999.04.20
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초록

The highly resolved absorption spectra of mer-[Cr(dpt)(Gly-Gly)]ClO4·H2O [dpt = di(3-aminopropyl)amine, H2Gly-Gly = glycylglycine] have been measured between 13000 cm-1 and 50000 cm-1 temperatures down to 2 K. The vibrational intervals were extracted by recording emission and far-infrared spectra. The characteristic infrared bands in meridional isomer were discussed. The four-teen electronic origins due to spin-allowed and spin-forbidden transitions were assigned. With the use of this electronic transitions, a ligand field optimization based on the exact known ligand geometry have been performed to determine more detailed bonding properties of Gly-Gly and dpt ligands. It is confirmed that the peptide nitrogen of the Gly-Gly has a weak π-donor property toward chrornium(Ⅲ) ion.

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참고문헌

  1. J. Chem. Soc., Chem. Comm. Murdoch, C.M.;Cooper, M.K.;Hambley, T.W.;Hunter, W.N.;Freedman, H.C.
  2. Polyhedron v.7 Subramanium, V.;Lee, K.W.;Garvey, R.G.;Hoggard, P.E.
  3. Polyhedron v.11 Choi, J.H.;Hoggard, P.E.
  4. Acta Cryst v.C51 Choi, J.H.;Suh, I.H.;Kwak, S.H.
  5. North Dakota State University Subramaniam, V.
  6. Inorg. Chim. Acta. v.216 Subramaniam, V.;Lee, K.W.;Hoggard, P.E,
  7. Inorg. Chem. v.25 Schonherr, T.
  8. T. Bull. Chem. Soc. Jpn. v.61 Schmidtke, H.H.;Adamsky, H.;Schonherr, T.
  9. Top. Curr. Chem. v.171 Hoggard, P.E.
  10. Inorg. Chim. Acta. v.221 Schonherr, T.;Wiskemann, R.;Mootz, D.
  11. Top. Curr. Chem. v.191 Schonherr, T.
  12. Bull. Chem. Soc. Jpn. v.68 Schonherr, T.;Itoh, M.;Urushiyama, A.
  13. Inorg. Chim. Acta v.249 Fujihara, T;Schonherr, T.;Kaizaki, S.
  14. Inorg. Chem. v.35 Schonherr, T.;Atanasov. M.;Hauser, A.
  15. J. Photosci. v.3 Choi, J.H.
  16. J. Photosci. v.4 Choi, J.H.
  17. Bull. Korean Chem. Soc. v.18 Choi, J.H.;Oh, I.G.
  18. Bull. Korean Chem. Soc. v.18 Choi, J.H.
  19. Bull. Korean Chem. Soc. v.19 Choi, J.H.
  20. Bull. Korean Chem. Soc. v.20 Choi, J.H.
  21. Coord. Chem. Rev. v.70 Hoggard, P.E.
  22. J. Phys. Chem. v.93 Schonderr, T.;Spanier, J.;Schmidtke, H.H.
  23. Phys. Rev. v.57B Wermuth, M.;Riedener, T.;Gudel, H.U.
  24. Inorg. Chim. Acta v.6 Gainsford, A.R.;Schmidtke, H.H.
  25. Inorg. Chim. Acta. v.2 Schmidtke, H.H.;Garthoff, D.
  26. Inorg. Chim. Acta. v.155 Subramaniam, V.;Hoggard, P.E.
  27. Bull. Korean Chem. Soc. v.14 Choi, J.H.
  28. Bull. Korean Chem. Soc. v.14 Choi, J.H.;Oh, I.G.
  29. Bull. Korean Chem. Soc. v.15 Choi, J.H.
  30. Matrix Eigensystem Routines-EISPACK Guide Smith. B.T.;Boyle, J.M.;Dongarra, J.J.;Garbow, B.S.;Ikebe, Y.;Klema, V.C.;Moler, C.B.
  31. Naturforsch v.45A Schonherr, T.;Degen, J.Z.
  32. Phys. Rev. v.83 Trees, R.E.
  33. Inorg. Chem. v.18 Schonherr, T.;Schmidtke, H.H.
  34. Optimization Techniques with Fortran Kuester, J.L.;Mize, J.H.
  35. Multivariate Error Analysis Clifford, A.A.
  36. Coord. Chem. Rev. v.48 Vanquickenborne, L.G.;Ceulemans, A