Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Effect of Excess PbO on Grain Growth and Densification of (65)Pb(${Mg_{1/3}}{Nb_{2/3}}$)$O_3$-(35)$PbTiO_3$ Ceramics

(65)Pb(${Mg_{1/3}}{Nb_{2/3}}$)$O_3$-(35)$PbTiO_3$의 입자성장과 치밀화에 미치는 과량 PbO의 영향

  • Lee, Jong-Bong (Division of Metallurgical and Materials Engineering, Sunmmon University) ;
  • Hur, Tae-Moo (Division of Metallurgical and Materials Engineering, Sunmmon University) ;
  • Lee, Ho-Yong (Division of Metallurgical and Materials Engineering, Sunmmon University) ;
  • Choi, Kyun (School of Materials Science and Eng., and Creative Research Center for Microstructure Science of Materials, Seoul National University) ;
  • Kim, Doe-Yeon (School of Materials Science and Eng., and Creative Research Center for Microstructure Science of Materials, Seoul National University)
  • 이종봉 (선문대학교 재료금속공학부) ;
  • 허태무 (선문대학교 재료금속공학부) ;
  • 이호용 (선문대학교 재료금속공학부) ;
  • 최균 (서울대학교 재료공학부 재료미세조직 창의연구단) ;
  • 김도연 (서울대학교 재료공학부 재료미세조직 창의연구단)
  • Published : 2000.07.01
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Abstract

The effect of excess PbO(0, 1, 2, 4, and 8 mol%) on grain growth and densification of (65)Pb(Mg1/3Nb2/3)O3-(35)PbTiO3 [mol%] ceramics has been investigaetd. With increasing the amount of excess PbO and sintering time, densities of sintered samples decreased gradually. The samples containing less than 1 mol% of PbO showed normal grain growth behavior, however abnormal grain growth was observed to occur in the samples with more than 2 mol% of PbO. In the samples with more than 2 mol% of PbO, the number of abnormal grains decreased and thus the average grain size became smaller with increasing the amount of excess PbO. These results demonstrated that the abnormal grain growth started to occur when a critical amount of excess PbO was added to a (65)Pb(Mg1/3Nb2/3)O3-(35)PbTiO3 sample. Since PMN-PT grains in a liquid matrix were angular, the observed abnormal grain growth was explained to proceed through the two dimensional nucleation process.

Keywords

References

  1. Handbook of Chemistry and Physics, 67th ed. R. C. Weast
  2. Piezoelectric Ceramics B. Jaffe;W. R. Cook, Jr.;H. Jaffe
  3. Mater. Res. Bull. v.25 Pseudo-Binary ? Phase Diagram and Crystal Growth of ? [PMN] Z. G. Ye;P. Tissot;H. Schmid
  4. Solid State Communic v.7 PbO Vapour Pressure in the ? System K. H. Hardtl;H. Rau
  5. J. Am. Ceram. Soc. v.71 Effect of Excess PbO on the Sintering Characteristics and Dielectric Properties of ? -PbTiO₃-based Ceramics J. P. Guha;D. J. Hong;H. U. Anderson
  6. J. Kor. Ceram. Soc. v.35 Abnormal Grain Growth Induced by Excess PbO in ?-(35)PbTiO₃Ceramics H. Y. Lee;H. M. Chan;M. P. Harmer
  7. J. Eur. Ceram. Soc. v.19 Pressureless Sintering of PMN-PT Ceramics H. Yamada
  8. J. Mater. Res. v.14 Effects of PbO excess in ?-PbTiO₃Ceramics: Part I. Sintering and Dielectric properties M. Villegas;A. C. Caballero;M. Kosec;C. Moure;P. Duran;J. F. Fernandez
  9. J. Mater. Res. v.14 Effects of PbO excess in ?-PbTiO₃Ceramics: Part II. Microstructure development M. Villegas;J. F. Fernandez;A. C. Caballero;Z. Samardija;G. Drazic;M. Kosec
  10. Ferroelectr. Lett. v.12 Dielectric Behavior of Single Crystals near the ?-(x)PbTiO₃Morphotropic Phase Boundary T. R. Shrout;Z. P. Chang;N. Kim;S. Markgraf
  11. Jpn. J. Appl. Phys. v.35 The Role of Processing Variables in the Flux Growth of Lead Zinc Niobate-Lead Titanate Relaxor Ferroelectric Single Crystals M. L. Mulvihill;S. E. Park;G. Risch;Z. Li;K. Uchino;T. R. Schrout
  12. Ferroelectrics v.207 Electric Field Induced Anisotropy in Electrostrictive ?-PbTiO₃Crystals S. E. Park;T. R. Shrout;P. Bridenbaugh;J. Rottenberg;G. M. Loiacono
  13. Science v.275 Shape-Changing Crystals Get Shifter R. F. Service
  14. IEEE Trans. Ultrason. Ferroelectr. Freq. Control v.44 Characteristics of Relaxor-Based Piezoelectric Single Crystals for Ultrasonic Transducers S. E. Park;T. R. Shrout
  15. Mater. Res. Innovations v.1 Relaxor-Based Ferroelectric Single Crystals for Clectromechanical Actuators S. E. Park;T. R. Shrout
  16. J. Appl. Phys. v.82 Ultrahigh Strain and Piezoelectric Behavior in Relaxor Based Ferroelectric Single Crystals S. E. Park;T. R. Shrout
  17. Proceedings on SPIE's International Symposium on Medical Imaging v.3341 Innovations in Piezoelectric Materials for Ultrasound Transducers T. R. Shrout;S. E. Park;P. Lopath;R. Meyer;T. Ritter;K. Shung
  18. Proceedings on SPIE's International Symposium on Medical Imaging v.3037 Relaxor-Based Single Crystal Materials for Ultrasonic Tranducer Applications S. E. Park;P. D. Lopath;K. K. Shung;T. R. Shrout
  19. J. Am. Ceram. Soc. v.81 Single Crystals of ? mol% PbTiO₃from Polycrystalline Precursors T. Li. A. M. Scotch;H. M. Chan;M. P. Harmer;S. E. Park;T. R. Shrout;J. R. Michael
  20. J. Am. Ceram. Soc. v.82 Growth of ? mol% PbTiO₃Single Crystals from (111) Substrates by Seeded Polycrystal Conversion A. Khan;F. Meschke;T. Li;A. M. Scotch;H. M. Chan;M. P. Harmer
  21. J. Mater. Res. v.14 Heteroepitaxial Growth of Bulk Single-Crystal ? mol% PbTiO₃from (111) SrTiO₃ T. Li;S. Wu;A. Khan;A. M. Scotch;H. M. Chan;M. P. Harmer
  22. Method for Growing Single Crystals from Polycrystalline Precursors M. P. Harmer;H. M. Chan;H. Y. Lee;A. M. Scotch;T. Li;F. Meschke;A. Khan
  23. Method for Producing a Single Crystal S. Matsuzawa;S. Mase
  24. Processing for Producing Single-Crystal Ceramics K. Kugimiya;K. Hirota;K. Matsuyama
  25. Fine Ceramics The Solid-phase Epitaxial Growth Method N. Yamamoto;S. Matsuzawa;S. Saito(ed.)
  26. Solid State Thermal Conversion of Polycrystalline Alumina to Sapphire Using a Seed Crystal C. E. Scott;J. M. Strok;L. M. Levinson
  27. J. Am. Ceram. Soc. v.47 Growth of Single Crystals of BaTiO₃by Exaggerated Grain Growth R. C. DeVries
  28. Proc. 2nd Japan International SAMPE, Dec. Preparation of BaTiO₃Single Crystals by Sintering T. Yamamoto;T. Sakuma
  29. J. Am. Ceram. Soc. v.77 Fabrication of Barium Titanate Single Crystals by Solid-State Grain Growth T. Yamamoto;T. Sakuma
  30. J. Eur. Ceram. Soc. v.17 Fabrication of BaTiO₃Single Crystals by Using the Exaggerated Grain Growth Method Y. S. Yoo;M. K. Kang;J. H. Han;H. Kim;D. Y. Kim
  31. J. Eur. Ceram. Soc. Fabrication of BaTiO₃Single Crystals Using Secondary Abnormal Grain Growth H. Y. Lee;J. S. Kim;D. Y. Kim
  32. Method for Producing a Single Crystal of Feffite S. Matsuazwa;S. Mase
  33. Grain Boundary Controlled Properties of Fine Ceramics Discontinuous Grain Growth and the Grain Boundary in a Solid-State Reaction Growth Method for Ferrite Single Crystals M. Imaeda;Y. Kozuka;S. Matsuzawa;K. Ishizaki(ed.);K. Niihara(ed.);M. Isotani(ed.);R. G. Ford(ed.)
  34. Mater. Res. Bull. v.17 Fabrication of Perovskite Lead Magnesium Niobate S. L. Swartz;T. R. Shrout
  35. Phase Transformations in Metals and Alloys D. A. Porter;K. E. Easterling
  36. Metall. Trans. A v.27A Abnormal Growth of Faceted (WC) Grains in a (Co) Liquid Matrix Y. J. Park;N. M. Hwang;D. Y. Yoon
  37. Abnormal Growth of Faceted Grains in Liquid Matrix Y. J. Park
  38. J. Am. Ceram. Soc. v.83 Growth of BaTiO₃Seed Grains by the Twin-Plane Reentrant Edge Mechanism K. Kang;Y. S. Yoo;D. Y. Kim;N. M. Hwang
  39. J. Eur. Ceram. Soc. v.20 Effect of Sintering Temperature on the Secondary Abnormal Grain Growth of BaTiO₃ H. Y. Lee;J. S. Kim;N. M. Hwang;D. Y. Kim