Sensing Characteristics of Thin Pt/$SnO_2$Composite Film to CO Gas

Pt/$SnO_2$복합체 박막의 CO 가스감지특성

  • 김동현 (부산대학교 무기재료공학과) ;
  • 이상훈 (부산대학교 무기재료공학과) ;
  • 송호근 (LG이노텍 연구소) ;
  • 김광호 (부산대학교 무기재료공학과)
  • Published : 2000.11.01

Abstract

본 연구에서는 Pt/Sn $O_2$박막의 CO 감지특성을 향상시키기 위하여 표면 형상을 제어하였다. Pt/Sn $O_2$계 박막센서의 최적 동작온도는 175$^{\circ}C$이었다. Pt가 12초 동안 증착된 Sn $O_2$가 200ppm의 CO 가스에 대하여 1.23의 최대감도를 나타내었고, 그 이상의 Pt 증착시간 증가에 따라 Sn $O_2$위의 Pt의 coverage가 증가하여 센서의 감도를 감소시켰다. 다층박막(multi-layer thin film)의 단층의 Pt/Sn $O_2$복합체 위에 다시 Sn $O_2$및 Pt의 cluster 층들을 연속적으로 증착함으로서 제작되었다. 단지 하나의 Pt 층만을 증착한 Sn $O_2$막보다 다층의 Pt/Sn $O_2$막이 더욱 우수한 감도( $R_{air}$/ $R_{co}$=1.72, CO: 200 ppm)를 나타내었다. Pt/Sn $O_2$다층박막의 우수한 감도의 원인은 Pt와 Sn $O_2$사이의 계면적 증대 때문인 것으로 생각되어 진다.다.

Keywords

References

  1. Anal. Chem. v.34 A New Detector for Gaseous Components Using Semiconductive Thin Film T. Seiyama;A. Kato;K. Nagatanui
  2. J. Electrochem. Soc. v.143 Selective CO Detection by Using Indium Oxide-Based Semiconductor H. Yamaura;J. Tamaki;K. Moriya;N. Miura;N. Yamazoe
  3. Sens. Actuators B. v.60 Nanoparticle Engineering for Gas Sensor Optimisation: Improved Sol-Gel Fabricated Nanocrystalline SnO₂ Thick Film Gas Sensor for NO₂ Detection by Calcination, Catalytic Metal Introduction and Grinding Treatments A. Di guez;A. Romano-Rodr guez;J.R. Morante;J. Kappler;N.B rsan;W.G pel
  4. Sens. Actuators B. v.45 Influence of the Deposition Conditions of SnO₂ Thin Films by Reactive Sputtering on the Sensitivity to Urban Pollutants M.C. Horrillo;P. Serrini;J. Santos;L. Manes
  5. Sens. Actuators B. v.21 Effect of Palladium Doping and Film Thickness on the H₂-gas Sensing Characteristics of SnO₂ K.H. Cha;H.C. Park;K.H. Kim
  6. Sens. Actuators B. v.56 Improvement of Long-term Stability in SnO₂-based Gas Sensor of Monitoring Offensive Odor J.H. Park;K.H. Kim
  7. Sens. Actuators B. v.24-25 SnO₂ Thin Films for Gas Sensor Prepared by R.F. Reactive Sputtering M. Di Giulio;G. Micocci;A. Serra;A. Tepore;R. Rella;P. Siciliano
  8. Sens. Actuators B. v.58 Influence of Tin Oxide Microstructure on the Sensitivity to Reductor Gases M.C. Horrillo;A. Serventi;D. Rickerby;J. Gutierrez
  9. J. Mat. Sci. Lett. v.15 A Study of the Gas Sensitivity of Alpha-Fe₂O₃ Sensors to CO and CH₄ J.S. Han;A.B. Yu;F.J. He;T. Yao
  10. Sens. Actuators B. v.24-25 An IR Study of CO-sensing Mechanism on Au/ZnO F. Boccuzzi;A. Chiorino;S. Tsubota;M. Haruta
  11. Thin Solid Films v.337 Sensor Properties of Pt Doped SnO₂ Thin Films for Detectiong CO A.V. Tadeev;G. Delabouglise;M. Labeau
  12. Sens. Actuators B. v.45 SnO₂ and SnO₂:Pt Thin Films Used as Gas Sensors M.de. la;L. Olvera;R. Asomoza
  13. Thin Solid Films v.304 CO Sensing Properties of SnO₂ Thin Films Prepared by the Sol-Gel Process R. Rella;A. Sera;P. Sicilino;L. Vasanelli;G. De;A. Licciulli
  14. Sens. Actuators B. v.32 CO-gas-induced Resistance Switching in SnO₂/ultrathin Pt Sandwich Structure A. Galdikas;A. Mironas;D. Senulien;A. Setkus
  15. Sens. Actuators B. v.23 Properties of Reactively Sputtered Tin Oxide Film as CO Gas Sensors M. Di Giulio;G. Micocci;R. Rella;P. Siciliano;A. Tepore
  16. J. Phys. D : Appl. Phys. v.29 Morphological, Chemical and Electrical Characterization of Pt-SnO₂ Thin Film Grown on Rough and Mechanically Polished Al₂O₃ Substrates A. Cricenti(et al.)
  17. J. Vac. Sci. Technol. A. v.14 Charcteristics of Reactively Sputtered Pt-SnO₂ Thin Films for CO Gas Sensors M. Di Giulio;G. Micocci;A. Serra;A. Tepore;R. Rella;P. Siciliano
  18. Sens. Actuators B. v.62 CO₂-sensing Characteristics of SnO₂ Thick Film by Coating Lanthaum Oxide D.H. Kim;J.Y. Yoon;H.C. Park;K.H. Kim
  19. Sens. Actuators B. v.55 Oxygen Flow Effect on Gas Sensitivity Properties of Tin Oxide Film Prepared by R.F. Sputtering V.V Kissine;S.A. Voroshilov;V.V. Sysoev
  20. Molecular Semiconductors J. Simon;J.J. Andre
  21. Sens. Actuators B. v.3 Conductivity Work Function and Catalytic Activity of SnO₂-based Sensors K.D. Schiebaum;U. Weimar;R. Kowalkowski;W.G. Pel
  22. Sens. Actuators B. v.24-25 Engineering of Oxide Surface and Metal/Oxide Interface for Chemical Sensors: Recent Trends K.D. Schierbaum