Preparation and properties of PbTiO$_3$thin films by MOCVD using ultrasonic spraying

초음파 분무 MOCVD법에 의한 PbTiO$_3$박막의 제조 및 특성

  • 이진홍 (경북대학교 무기재료공학과) ;
  • 김용환 (경북대학교 무기재료공학과) ;
  • 이상희 (경북대학교 무기재료공학과) ;
  • 박병옥 (경북대학교 무기재료공학과)
  • Published : 2000.06.01

Abstract

Lead titanate thin films were fabricated on Si(100) wafer and ITO-coated glass substrates by metal organic chemical vapor deposition using ultrasonic spraying. When the ratio (Ti/Pb) of starting materials was 1.2, the films deposited on Si wafer had a single perovskite phase. The films deposited on ITO-coated glass had higher growth rate than that on Si wafer. As deposition temperature was increased from $530^{\circ}C$ to $570^{\circ}C$, dielectric constant was increased due to the increase of crystallinity and grain size. At $570^{\circ}C$, dielectric constant and dielectric loss of the films were 205 and 0.016, respectively. When the deposition temperature is higher than $600^{\circ}C$, dielectric constant was decreased.

초음파분무를 이용한 MOCVD법으로 강유전체 $PbTiO_3$박막을 Si(100) wafer와 ITO-coated glass위에 제조하였다 Si 기판 위에 증착된 박막으로부터, 출발원료의 농도비(Ti/Pb)가 1.2일 때, 단일 perovskite 상을 얻을 수 있었다. ITO-coated glass 위에 증착된 박막은 Si기판 위에 제조된 박막보다 박막의 성장속도가 더 빠르며, 기판온도를 $530^{\circ}C$부터 $570^{\circ}C$까지 증가시켰을 때, 결절성과 입자 크기의 증가에 의해 유전상수는 증가하였다. $570^{\circ}C$에서의 유전상수 및 유전손실 값은 각각 205, 0.016을 나타내었다. 기판온도가 $600^{\circ}C$ 이상인 경우, 유전상수가 감소되는 경향을 보였다.

Keywords

References

  1. Thin Film Ferroelectric Materials and Devices R.Ramesh
  2. Thin Film Device Applications Kasturi Lal Chopra;Inderjeet Kaur
  3. IEEE. Trans on Ultrasonics, Ferroelectrics and Frequency Control v.38 no.6 J.Carrano;V.Chikarmano;J.Lee;W.Shepherd;N.Abt
  4. J. Am. Ceram. Soc. v.73 no.8 S.D.Ramamurthi;D.A.Payne
  5. J. Appl. Phys. v.60 no.2 H.Adachi;T.Mitsuyu;O.Yamazaki;K.Wasa
  6. Jpn. J. Appl. Phys. v.30 no.9B T.Imai;M.Okuyma;Y.Hamakawa
  7. Metal Alkoxides D.C.Bradley;R.C.Mehrotra
  8. Ceramic bulletin v.70 no.8 A.C.Pirre
  9. J. Kor. ceram. Soc. v.31 no.11 S.H.Kim;Y.J.Oh;C.E.Kim
  10. J. Vac. Sci. Tech. v.42 H.T.G.Hentzell(et al.)
  11. Ceramic Dielectrics and Capacitors J.M.Herbert
  12. Electrical Conductivity in Ceramics and Glass N.M.Tallan